Sulfenyl bromide

Sulfenyl bromide
General formula
Trichloromethanesulfenyl bromide
Chlorocarbonyl sulfenyl bromide

Sulfenyl bromides are a group of substances in organic chemistry with the general formula R – S – Br, more precisely they are bromides of sulfenic acid (R – S – OH). Trichloromethanesulfenyl bromide (Cl ₃ C-S-Br) and chlorocarbonylsulfenyl bromide (Cl-CO-S-Br) are examples of known sulfenyl bromides.

Manufacturing

Organosulfenyl chlorides (R – S – Cl) react with hydrobromic acid (HBr) to form sulfenyl bromides.

Individual evidence

↑ ^a ^b Rosana M. Romano, Carlos O. Della Védova, Anthony J. Downs, Tim M. Greene: Matrix Photochemistry of syn- (Chlorocarbonyl) sulfenyl Bromide, syn-ClC (O) SBr: Precursor to the Novel Species anti- ClC (O) SBr, syn-BrC (O) SCl, and BrSCl , J. Am. Chem. Soc. 2001, 123, 24, 5794-5801, doi: 10.1021 / ja010252f .
↑ Joseph Nils Ospenson (California Spray-Chemical Corp.): Preparation of organic sulfenyl bromides , U.S. Patent 2,824,136 .

[Romano-1] Rosana M. Romano, Carlos O. Della Védova, Anthony J. Downs, Tim M. Greene: Matrix Photochemistry of syn- (Chlorocarbonyl) sulfenyl Bromide, syn-ClC (O) SBr: Precursor to the Novel Species anti- ClC (O) SBr, syn-BrC (O) SCl, and BrSCl , J. Am. Chem. Soc. 2001, 123, 24, 5794-5801, doi: 10.1021 / ja010252f .

[Ospenson-2] Joseph Nils Ospenson (California Spray-Chemical Corp.): Preparation of organic sulfenyl bromides , U.S. Patent 2,824,136 .