Jarosite: Difference between revisions
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In the jarosite-alunite series Al may substitute for Fe and a complete solid solution series between jarosite and alunite, KAl<sub>3</sub>(SO<sub>4</sub>)<sub>2</sub>(OH)<sub>6</sub>, probably exists, but intermediate members are rare. The material from [[Kopec]], [[Czech Republic]], has about equal Fe and Al, but the amount of Al in jarosite is usually small. |
In the jarosite-alunite series Al may substitute for Fe and a complete solid solution series between jarosite and alunite, KAl<sub>3</sub>(SO<sub>4</sub>)<sub>2</sub>(OH)<sub>6</sub>, probably exists, but intermediate members are rare. The material from [[Kopec]], [[Czech Republic]], has about equal Fe and Al, but the amount of Al in jarosite is usually small. |
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In the jarosite-natrojarosite series Na substitutes for K to at least Na/K = 1:2.4 but the pure sodium end member NaFe<sup>3+</sup><sub>3</sub>(SO<sub>4</sub>)<sub>2</sub>(OH)<sub>6</sub> is not known in nature. Minerals with Na > K are known as [[natrojarosite]]. End member formation (jarosite and natrojarosite) is favoured by a low temperature environment, less than 100 °C, and is illustrated by the oscillatory zoning of jarosite and natrojarosite found in samples from the Apex Mine, Arizona, and [[Gold Hill, Utah]]. This indicates that there is a wide [[miscibility |
In the jarosite-natrojarosite series Na substitutes for K to at least Na/K = 1:2.4 but the pure sodium end member NaFe<sup>3+</sup><sub>3</sub>(SO<sub>4</sub>)<sub>2</sub>(OH)<sub>6</sub> is not known in nature. Minerals with Na > K are known as [[natrojarosite]]. End member formation (jarosite and natrojarosite) is favoured by a low temperature environment, less than 100 °C, and is illustrated by the oscillatory zoning of jarosite and natrojarosite found in samples from the Apex Mine, Arizona, and [[Gold Hill, Utah]]. This indicates that there is a wide [[miscibility gap]] between the two end members,<ref name=AM92>American Mineralogist (2007) 92:444-447</ref> and it is doubtful whether a complete series exists between jarosite and natrojarosite. |
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In [[hydroniumjarosite]]<ref name=AM921464>American Mineralogist (2007) 92:1464-1473</ref> the [[hydronium]] ion H<sub>3</sub>O<sup>+</sup> can also substitute for K<sup>+</sup>, with increased hydronium ion content causing a marked decrease in the lattice parameter ''c'', although there is little change in ''a''.<ref name=AM50>American Mineralogist (1965) 50:1595-1607</ref> Hydroniumjarosite will only form from alkali-deficient solutions, as alkali-rich jarosite forms preferentially. |
In [[hydroniumjarosite]]<ref name=AM921464>American Mineralogist (2007) 92:1464-1473</ref> the [[hydronium]] ion H<sub>3</sub>O<sup>+</sup> can also substitute for K<sup>+</sup>, with increased hydronium ion content causing a marked decrease in the lattice parameter ''c'', although there is little change in ''a''.<ref name=AM50>American Mineralogist (1965) 50:1595-1607</ref> Hydroniumjarosite will only form from alkali-deficient solutions, as alkali-rich jarosite forms preferentially. |
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Revision as of 11:26, 3 March 2015
| Jarosite | |
|---|---|
 Jarosite on quartz from the Arabia District, Pershing County, Nevada | |
| General | |
| Category | Sulfate minerals |
| Formula (repeating unit) | KFe3+3(OH)6(SO4)2 |
| Strunz classification | 07.BC.10 |
| Dana classification | 30.2.5.1 |
| Crystal system | Trigonal |
| Space group | Trigonal 3 2/m hexagonal scalenohedral |
| Unit cell | a = 7.304 Å, c = 17.268 Å; Z=3 |
| Identification | |
| Formula mass | 500.8 g |
| Color | Amber yellow or dark brown |
| Crystal habit | Crystals are usually pseudocubic or tabular, also as granular crusts, nodules, fibrous masses or concretionary. |
| Cleavage | Distinct on {0001} |
| Fracture | Uneven to conchoidal |
| Tenacity | Brittle |
| Mohs scale hardness | 2.5 - 3.5 |
| Luster | Subadamantine to vitreous, resinous on fractures |
| Streak | light yellow |
| Diaphaneity | Transparent to translucent |
| Specific gravity | 2.9 to 3.3 |
| Optical properties | Uniaxial (-), usually anomalously biaxial with very small 2V |
| Refractive index | nω = 1.815 to 1.820; nε = 1.713 to 1.715 |
| Birefringence | 0.102 to 0.105 |
| Pleochroism | E colorless, very pale yellow, or pale greenish yellow, O deep golden yellow or reddish brown |
| Solubility | Insoluble in water. Soluble in HCl. |
| Other characteristics | Strongly pyroelectric. Non-fluorescent. Barely detectable radioactivity |
| References | [1][2][3] |
Jarosite is a basic hydrous sulfate of potassium and iron with a chemical formula of KFe3+3(OH)6(SO4)2. This sulfate mineral is formed in ore deposits by the oxidation of iron sulfides. Jarosite is often produced as a byproduct during the purification and refining of zinc and is also commonly associated with acid mine drainage and acid sulfate soil environments.
Physical properties
Jarosite has a trigonal crystal structure and is brittle, with basal cleavage, a hardness of 2.5-3.5, and a specific gravity of 3.15-3.26. It is translucent to opaque with a vitreous to dull lustre, and is colored dark yellow to yellowish-brown. It can sometimes be confused with limonite or goethite with which it commonly occurs in the gossan (oxidized cap over an ore body). Jarosite is an iron analogue of the potassium aluminium sulfate, alunite.
Solid solution series
The alunite supergroup includes the alunite, jarosite, beudantite, crandallite and florencite subgroups. The alunite supergroup minerals are isostructural with each other and substitution between them occurs, resulting in several solid solution series. The alunite supergroup has the general formula AB3(TO4)2(OH)6. In the alunite subgroup B is Al, and in the jarosite subgroup B is Fe3+. The beudantite subgroup has the general formula AB3(XO4)(SO4)(OH)6, the crandallite subgroup AB3(TO4)2(OH)5.H2O and the florencite subgroup AB3(TO4)2(OH)5or6.
In the jarosite-alunite series Al may substitute for Fe and a complete solid solution series between jarosite and alunite, KAl3(SO4)2(OH)6, probably exists, but intermediate members are rare. The material from Kopec, Czech Republic, has about equal Fe and Al, but the amount of Al in jarosite is usually small.
In the jarosite-natrojarosite series Na substitutes for K to at least Na/K = 1:2.4 but the pure sodium end member NaFe3+3(SO4)2(OH)6 is not known in nature. Minerals with Na > K are known as natrojarosite. End member formation (jarosite and natrojarosite) is favoured by a low temperature environment, less than 100 °C, and is illustrated by the oscillatory zoning of jarosite and natrojarosite found in samples from the Apex Mine, Arizona, and Gold Hill, Utah. This indicates that there is a wide miscibility gap between the two end members,[4] and it is doubtful whether a complete series exists between jarosite and natrojarosite.
In hydroniumjarosite[5] the hydronium ion H3O+ can also substitute for K+, with increased hydronium ion content causing a marked decrease in the lattice parameter c, although there is little change in a.[6] Hydroniumjarosite will only form from alkali-deficient solutions, as alkali-rich jarosite forms preferentially.
Divalent cations may also substitute for the monovalent cation K+ in the A site.[7] Charge balance may be achieved in three ways.
- Firstly by replacing two monovalent cations by one divalent cation, and leaving an A site vacancy, as in plumbogummite, Pb2+Al3(PO4)2(OH)5.H2O, which is a member of the crandallite subgroup.
- Secondly by incorporating divalent ions in the B sites, as in osarizawaite, Pb2+Cu2+Al2(SO4)2(OH)6, alunite subgroup, and beaverite, Pb2+Cu2+(Fe3+,Al)2(SO4)2(OH)6, jarosite subgroup.
- Thirdly by replacing divalent anions with trivalent anions, as in beudantite, PbFe3+3(AsO4)3−(SO4)(OH)6, beudantite subgroup.
History
Jarosite was first described in 1852 by August Breithaupt in the Barranco del Jaroso in the Sierra Almagrera (near Los Lobos, Cuevas del Almanzora, Almería, Spain). The name jarosite is also directly derived from Jara, the Spanish name of a yellow flower that belongs to the genus cistus and grows in this sierra. The mineral and the flower have the same color.
In 2004 jarosite was detected on Mars by a Mössbauer spectrometer on the MER-B rover, which has been interpreted as strong evidence that Mars once possessed large amounts of liquid water.
Mysterious spheres of clay, 1.5 to 5 inches in diameter, covered with jarosite have recently been discovered beneath the Temple of the Feathered Serpent an ancient six level stepped pyramid 30 miles from Mexico City.[8]
Use in materials science
Jarosite is also a more generic term denoting an extensive family of compounds of the form AM3(OH)6(SO4)2, where A+ = Na, K, Rb, NH4, H3O, Ag, Tl and M3+ = Fe, Cr, V. In condensed matter physics and materials science they are renowned for containing layers with kagome lattice structure, relating to geometrically frustrated magnets.[9][10]
See also
References
- ^ Gaines et al (1997) Dana's New Mineralogy Eighth Edition, Wiley
- ^ http://www.mindat.org/min-2078.html
- ^ http://rruff.geo.arizona.edu/doclib/hom/jarosite.pdf
- ^ American Mineralogist (2007) 92:444-447
- ^ American Mineralogist (2007) 92:1464-1473
- ^ American Mineralogist (1965) 50:1595-1607
- ^ American Mineralogist (1987) 72:178-187
- ^ Discovery News (2013) "Robot Finds Mysterious Spheres in Ancient Temple"
- ^ Harrison, A. (2004). "First catch your hare: the design and synthesis of frustrated magnets". J. Phys.: Condens. Matter. 16 (9–12): S553–S572. Bibcode:2004JPCM...16S.553H. doi:10.1088/0953-8984/16/11/001.
- ^ Wills, A. S.; Harrison, A.; Ritter, C.; Smith, R.; et al. (2000). "Magnetic properties of pure and diamagnetically doped jarosites: Model kagomé antiferromagnets with variable coverage of the magnetic lattice". Phys. Rev. B. 61 (9): 6156–6169. Bibcode:2000PhRvB..61.6156W. doi:10.1103/PhysRevB.61.6156.
{{cite journal}}: Explicit use of et al. in:|first=(help)
- Palache C., Berman H., and Frondel C. (1951) Dana’s system of mineralogy, (7th edition), v. II, 560–562.
- Webmineral data
- Cornell University (2004) How an obscure mineral provided a vital clue to Martian water.
- Discovery News (2013) "Robot Finds Mysterious Spheres in Ancient Temple"