Jump to content

Phenyl group

From Wikipedia, the free encyclopedia

This is an old revision of this page, as edited by ChemGardener (talk | contribs) at 18:54, 15 September 2008 (Reverted edits by 76.67.5.136 (talk) to last version by J.delanoy). The present address (URL) is a permanent link to this revision, which may differ significantly from the current revision.

The structure of the phenyl group

In organic chemistry, the phenyl group or phenyl ring (often abbreviated as -Ph) is the functional group with the formula

-C6H5

where the six carbon atoms are arranged in a cyclic ring structure. This hydrophobic, highly stable and aromatic hydrocarbon unit can be found in many organic compounds. It can be thought of as being derived from benzene (C6H6). In fact, in chemical literature benzene itself is sometimes denoted as Ph. One of the simplest phenyl containing compounds is phenol, C6H5OH. The resonance stability of phenol makes it a stronger acid than that of aliphatic alcohols such as ethanol (pKa = 10 vs. 16-18).

Presence of a phenyl group typically results in an 1H-NMR shift around 7.7ppm.

Phenyl groups can also be found in polymers such as polystyrene.

The phenyl group belongs to the Aryl group of compounds.

The phenyl group differs from the benzyl functional group in that benzyls have an extra CH2.