Grimm's hydride shift theorem

The Grimm's hydride shift law (also hydride shift law ) allows a comparison of hydrogen-containing atom groups with atoms in the periodic table of the elements . The set is named after its discoverer, Hans G. Grimm .

An atom that is up to four places in front of a noble gas, by absorbing n = 1, 2, 3, 4 hydrogen atoms , receives properties of the elements in the periodic table by n groups to the right of it.

Examples:

-OH, -NH ₂ and -CH ₃ , like the halogens, occur as monovalent ligands .
The ammonium ion NH ₄⁺ is - like the positively charged ions of the alkali metals - colorless and forms salts that are usually readily soluble in water.

Individual evidence

^ AF Holleman , E. Wiberg , N. Wiberg : Textbook of Inorganic Chemistry . 101st edition. Walter de Gruyter, Berlin 1995, ISBN 3-11-012641-9 , p. 654.
^ E. Schweda: Jander / Blasius: Inorganic Chemistry I - Introduction & Qualitative Analysis . 17th edition. Hirzel, 2012, ISBN 978-3-7776-2134-0 . Pp. 73, 294

[1] AF Holleman , E. Wiberg , N. Wiberg : Textbook of Inorganic Chemistry . 101st edition. Walter de Gruyter, Berlin 1995, ISBN 3-11-012641-9 , p. 654.

[2] E. Schweda: Jander / Blasius: Inorganic Chemistry I - Introduction & Qualitative Analysis . 17th edition. Hirzel, 2012, ISBN 978-3-7776-2134-0 . Pp. 73, 294