Thiyl radicals
In organic chemistry, thiyl radicals are reactive intermediates from the group of reactive sulfur species , which are derived from thiols (mercaptans). Under the influence of peroxides , thiols turn into reactive thiyl radicals:
Thiyl radicals are extremely electrophilic and react particularly quickly with electron-rich C = C double bonds in alkenes , such as. B. styrene or vinyl ether .
Individual evidence
- ^ Ivan Ernest: Binding, structure and reaction mechanisms in organic chemistry , Springer-Verlag, 1972, p. 315, ISBN 3-211-81060-9 .