Peridinin: Difference between revisions

From Wikipedia, the free encyclopedia
Content deleted Content added
m Adding category Category:Acetate esters (using HotCat)
m Adding category Category:Furones (using HotCat)
Line 37: Line 37:
[[Category:Epoxides]]
[[Category:Epoxides]]
[[Category:Acetate esters]]
[[Category:Acetate esters]]
[[Category:Furones]]


[[pl:Peridinina]]
[[pl:Peridinina]]

Revision as of 09:06, 19 September 2010

Peridinin
Names
IUPAC name
Acetic acid [(1S,3R)-3-hydroxy-4-[(3E,5E,7E,9E,11Z)-11-[4-[(E)-2-[(1S,4S,6R)-4-hydroxy-2,2,6-trimethyl-7-oxabicyclo[4.1.0]heptan-1-yl]vinyl]-5-oxo-2-furylidene]-3,10-dimethylundeca-1,3,5,7,9-pentaenylidene]-3,5,5-trimethylcyclohexyl] ester
Identifiers
3D model (JSmol)
  • [H][C@@](/[C@@](C)=C/C=C/C=C/C=C(C)/C=C2C=C(/C=C/[C@@]3(O4)[C@]4(C)C[C@@H](O)CC(C)3C)C(O\2)=O)=C=C1[C@](C)(O)C[C@@H](OC(C)=O)CC(C)1C
Properties
C39H50O7
Molar mass 630.81 g/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Peridinin is a light-harvesting carotenoid, a pigment associated with chlorophyll and found in the peridinin-chlorophyll-protein (PCP) light-harvesting complex in dinoflagellates, best studied in Amphidinium carterae.[1] The PCP complex is unique in its high ratio of peridinin to chlorophyll; most light-harvesting complexes contain more chlorophyll than carotenoids, but the PCP contains eight peridinin and two chlorophyll molecules arranged to promote peridinin-chlorophyll energy transfer. The PCP complex is a protein trimer with an unusual alpha solenoid protein fold.

The peridinin-chlorophyll-protein light-harvesting complex. The peridinin molecules are pink and the chlorophyll molecules are black.


References

  1. ^ Hofmann E, Wrench PM, Sharples FP, Hiller RG, Welte W, Diederichs K (1996). "Structural basis of light harvesting by carotenoids: peridinin-chlorophyll-protein from Amphidinium carterae". Science. 272 (5269): 1788–1791. doi:10.1126/science.272.5269.1788. PMID 8650577.{{cite journal}}: CS1 maint: multiple names: authors list (link)