Ammonium 6 molybdenum colate (II)

Crystal structure
	Hexamolybdoniccolate ion in ammonium 6-molybdoniccolate
General
Surname	Ammonium 6 molybdenum colate (II)
other names	Ammonium hexa-μ3-hydroxynickelate hexa-μ-oxododecaoxohexamolybdate (4-)
Ratio formula	(NH 4 ) 4 H 6 NiMo 6 O 24
Brief description	light blue crystalline solid
External identifiers / databases
Wikidata	Q25393403
properties
Molar mass	1096.59 g mol −1
Physical state	firmly
solubility	moderately soluble in cold, somewhat better in hot water
safety instructions
GHS hazard labeling ; no classification available
GHS hazard labeling ; no classification available
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

When ammonium-6-molybdoniccolat (II) is a polyoxometalate species of molybdenum .

presentation

To prepare ammonium 6-molybdonic colate (II), ammonium heptamolybdate tetrahydrate is reacted with nickel sulfate in boiling water . Then ammonium chloride is added.

properties

Ammonium-6-molybdoniccolate (II) is a heteropolymolybdate that forms light blue crystals. It crystallizes in the space group P 2 ₁ / a (space group no. 14, position 3) with the lattice parameters a = 11.99 Å , b = 11.13 Å, c = 11.38 Å and β = 109.3 ° . Template: room group / 14.3

Individual evidence

↑ ^a ^b ^c ^d Georg Brauer (Ed.) U. a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume III, Ferdinand Enke, Stuttgart 1981, ISBN 3-432-87823-0 , p. 1787.
↑ This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
↑ Kurz, Philipp; Stock, Norbert: Synthetic Inorganic Chemistry: Basic Course. Berlin: Walter de Gruyter, 2013. ISBN 978-3-11-025875-2 , p. 78.
↑ U. Lee, H.-C. Joo, JS Kwon: Tetraammonium hexahydrogen hexamolybdonickelate (II) tetrahydrate, (NH ₄ ) ₄ [H ₆ NiMo ₆ O ₂₄ ] · 4 H ₂ O. In: Acta Crystallographica , E58, 2002, pp. I6-i8, doi: 10.1107 / S1600536801021109 .

[brauer-1] Georg Brauer (Ed.) U. a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume III, Ferdinand Enke, Stuttgart 1981, ISBN 3-432-87823-0 , p. 1787.

[NV-2] This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.

[3] Kurz, Philipp; Stock, Norbert: Synthetic Inorganic Chemistry: Basic Course. Berlin: Walter de Gruyter, 2013. ISBN 978-3-11-025875-2 , p. 78.

[4] U. Lee, H.-C. Joo, JS Kwon: Tetraammonium hexahydrogen hexamolybdonickelate (II) tetrahydrate, (NH ₄ ) ₄ [H ₆ NiMo ₆ O ₂₄ ] · 4 H ₂ O. In: Acta Crystallographica , E58, 2002, pp. I6-i8, doi: 10.1107 / S1600536801021109 .