Escape line
Escape lines or escape peaks are spurious spectral lines , which in the X-rays - and gamma spectroscopy occur and z. B. can simulate the presence of non-existent radionuclides in the measured sample.
The name (English to escape ) indicates the origin of these lines: these are detection events in which not the entire energy of the photon is converted in the radiation detector , but a certain, always equal part of the energy returns to the detector leaves. This makes an additional peak in the spectrum , an image (a kind of reduced ghost image ) of the actual photo peak visible with a correspondingly lower energy.
causes
X-ray fluorescence
X-ray fluorescence as the cause of escape lines is most likely if the energy E of the incident photons is not too high above the area of the K-lines of the detector material, i.e. H. approximately between 10 and 100 keV . The vacancy that has arisen in the K-shell (rarely in higher shells) through photoionization is reoccupied with the emission of an X-ray photon from the upper shells. If this X-ray photon leaves the detector material, it leads z. B. the energy E K of a quantum with it. The kinetic energy of the electron, on the other hand, is converted into collisions in the detector, and the other, lower-energy photons that are created when electrons of the higher shells "move up" have only a low probability of escape. Therefore, in addition to the photopeak at energy E, an escape peak at E - E K is formed .
X-ray escape lines from other energy levels ( etc.) are rarer according to the probabilities of these transitions.
Pair formation
If the energy of the incident photon is above the rest energy of two electrons (1022 keV), pairs can form in the detector . The resulting positron is captured in the detector material and forms a positronium , which is then radiated in two photons of 511 keV each . If one or both of these photons can leave the detector - the easier the smaller the detector crystal - the photopeak ( full energy peak , FEP) of the energy E escape lines at E - 511 keV ( single escape peak ) and E - 1022 are formed keV ( double escape peak ).
In the gamma spectrum shown there is a component with an energy of 4.4 MeV. Single and double escape lines for this FEP are clearly visible.