Hans Sillescu

from Wikipedia, the free encyclopedia

Hans Sillescu (born October 5, 1936 in Frankfurt am Main ) is a German chemist ( physical chemistry ). He is a professor emeritus at Johannes Gutenberg University Mainz .

Life

Sillescu studied chemistry from 1956 at the Johann Wolfgang Goethe University in Frankfurt am Main with a diploma in 1961 and a doctorate in 1964 (nuclear quadrupole coupling in some cobalt (III) complexes) under Hermann Hartmann , under whom he set up an NMR group and initially NMR ( according to a research focus of his teacher Hartmann) applied to complex chemistry. As a post-doctoral student he was at the University of California, Los Angeles with Daniel Kivelson and at Harvard University with Roy Gordon in 1966/67 and began to work on dynamic NMR studies. In 1968 he completed his habilitation with Hartmann at the Johann Wolfgang Goethe University in Frankfurt am Main (theory of spin-lattice relaxation in liquids).

In 1971 he became a professor for physical chemistry in Frankfurt. From 1975 until his retirement in 2002 he was a professor in Mainz (as the successor to Günter Victor Schulz ). In 1987/88 he was dean of the chemistry department there.

He deals with the theoretical and experimental investigation of slow, complex molecular dynamics, in (complex) liquids, polymers (where he is especially known for NMR studies with deuteron NMR), colloids and in the dynamics of the glass transition. He uses NMR spectroscopy (investigation of very slow rotational and translational movements), dynamic light scattering (photon correlation spectroscopy, forced Rayleigh scattering) and light microscopy with digital image processing. From 1983 to 1987 he was the spokesman for the Collaborative Research Center Chemistry and Physics of Macromolecules (which existed from 1968 to 1987). He was also involved in the SFB Glass Condition and Glass Transition of Non-Metallic Amorphous Materials .

As a hobby he plays the cello.

Fonts (selection)

  • Nuclear Magnetic Resonance: Introduction to Theoretical Basics, Springer Verlag 1966
  • with Daniel Kivelson: Theory of Spin-Lattice Relaxation in Classical Liquids, Journal of Chemical Physics, Volume 48, 1968, p. 3494
  • Theory of Molecular Reorientation in Liquids: Magnetic Spin Resonance Line Shapes, Journal of Chemical Physics, Volume 54, 1971, p. 2110
  • with Hans Wolfgang Spieß: Solid echoes in the slow motion region, Journal of Magnetic Resonance, Volume 42, 1981, pp. 381–389
  • Irreversible processes, American Journal of Physics, Volume 41, 1973, p. 611
  • with Inyong Chang: Heterogeneity at the Glass Transition: Translational and Rotational Self-Diffusion, J. of Physical Chemistry B, Volume 101, 1997, pp. 8794-8801
  • Multidimensional nuclear magnetic resonance in complex liquids analyzed by a simple model for non ‐ Markovian molecular reorientation, J. Chem. Physics, Volume 104, 1996, 4877
  • Heterogeneity at the glass transition: a review, Journal of Non-Crystalline Solids, Volume 243, 1999, pp. 81-108
  • with R. Böhmer, G. Diezemann, G. Hinze: Heterogeneity at the glass transition: what do we know?, J. Non-Cryst. Solids, 307-310, 2002, pp. 16-23
  • with A. Doess, M. Paluch, G. Hinze: From strong to fragile glass formers: secondary relaxations in polyalcohols, Phys. Rev. Letters, Volume 88, 2002, pp. 95701-1-4

literature

  • Hans Wolfgang Spiess , Hans Sillescu on his 65th birthday, reports of the Bunsen Society 5/2001, p. 139

Web links

Individual evidence

  1. Published in Theoretica Chimica Acta 1964.