Pentanitroaniline
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| General | ||||||||||
| Surname | Pentanitroaniline | |||||||||
| Molecular formula | C 6 H 2 N 6 O 10 | |||||||||
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| Molar mass | 318.11 g mol −1 | |||||||||
| Physical state |
firmly |
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| As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . | ||||||||||
Pentanitroaniline is an explosive . It consists of a benzene ring with one amino group (–NH 2 ) and five nitro groups (–NO 2 ) as substituents.
The nitration of 3,5-dinitroaniline with anhydrous nitrating acid leads to pentanitroaniline in 52% yield. The oxidation of pentanitroaniline with peroxodisulfuric acid produces hexanitrobenzene .
Individual evidence
- ↑ This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
- ^ Jai Prakash Agrawal, Robert Hodgson: Organic Chemistry of Explosives , John Wiley & Sons, 2006, ISBN 978-0-470-02967-1 , p. 379 ( limited preview in Google book search).
- ^ Arnold T. Nielsen, Ronald L. Atkins, William P. Norris: "Oxidation of poly (nitro) anilines to poly (nitro) benzenes. Synthesis of hexanitrobenzene and pentanitrobenzene ", J. Org. Chem. , 1979 , 44 (7), pp. 1181-1182 ( doi : 10.1021 / jo01321a041 ).
- ↑ Ronald L. Atkins, Richard A. Hollins, William S. Wilson: "Synthesis of polynitro compounds. Hexasubstituted benzenes ", J. Org. Chem. , 1986 , 51 (17), pp. 3261-3266 ( doi : 10.1021 / jo00367a003 ).