Ureide

from Wikipedia, the free encyclopedia
Ureide (examples)
N-acetylurea
N -acetylurea (acetic acid derivative)
Barbituric acid
Barbituric acid (malonic acid derivative)
Parabanic acid
Parabanic acid (oxalic acid derivative)

Urea are organochemical substances derived from urea (H 2 N – CO-NH 2 ) and carboxylic acids (R – COOH). The ureide of acetic acid is acetylurea (H 3 C – CO – HN – CO-NH 2 ).

The cyclic ureals, which are derived from aliphatic dicarboxylic acids ( oxalic acid , malonic acid, etc.) are of particular importance .

According to IUPAC rule C-971.2, such compounds are to be referred to as N- acylureas or ureido derivatives.

Manufacturing

Urea is synthetically accessible through the action of carboxylic acid chlorides or carboxylic acid anhydrides on urea. Barbituric acid - the cyclic ureide of malonic acid is made from urea and a diester of malonic acid in the presence of sodium ethanolate.

Web links

Commons : Acylureas  - collection of images, videos and audio files

Individual evidence

  1. ^ Brockhaus ABC Chemie , VEB FA Brockhaus Verlag, Leipzig 1965, p. 1465.
  2. ^ Otto-Albrecht Neumüller (editor): Römpps Chemie Lexikon , 8th edition, Frank'sche Verlagshandlung, Stuttgart 1983, ISBN 3-440-04513-7 , pp. 4444-4445.
  3. ^ Siegfried Hauptmann : Organic Chemistry , 2nd revised edition, VEB Deutscher Verlag für Grundstoffindindustrie, Leipzig 1985, ISBN 3-342-00280-8 , p. 468.