Tetrafluorobenzenes

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Tetrafluorobenzenes
Surname 1,2,3,4-tetrafluorobenzene 1,2,3,5-tetrafluorobenzene 1,2,4,5-tetrafluorobenzene
Structural formula Structure of 1,2,3,4-tetrafluorobenzene Structure of 1,2,3,5-tetrafluorobenzene Structure of 1,2,4,5-tetrafluorobenzene
CAS number 551-62-2 2367-82-0 327-54-8
PubChem 11084 16910 9474
Molecular formula C 6 H 2 F 4
Molar mass 150.07 g mol −1
Physical state liquid
Melting point −42 ° C −46.25 ° C 4 ° C
boiling point 95 ° C 84.4 ° C 90 ° C
density 1.4 g cm −3 (25 ° C) 1.393 g cm −3 (25 ° C) 1,344 g cm −3 (25 ° C)
GHS
labeling
02 - Highly / extremely flammable 07 - Warning
danger
H and P phrases 225-315-319-335
no EUH phrases
210-261-305 + 351 + 338

In chemistry, the tetrafluorobenzenes form a group of substances consisting of a benzene ring with four fluorine atoms  (–F) as substituents . Their different arrangement results in three constitutional isomers with the empirical formula C 6 H 2 F 4 .

properties

The boiling points of the three isomers are relatively close to one another, while their melting points differ more clearly. Due to its symmetry, 1,2,4,5-tetrafluorobenzene has the highest melting point of 4 ° C.

Individual evidence

  1. a b c d data sheet 1,2,3,4-tetrafluorobenzene from Sigma-Aldrich , accessed on April 22, 2017 ( PDF ).
  2. a b David R. Lide (Ed.): CRC Handbook of Chemistry and Physics . 90th edition. (Internet version: 2010), CRC Press / Taylor and Francis, Boca Raton, FL, Physical Constants of Organic Compounds, pp. 3-474.
  3. a b c d data sheet 1,2,4,5-tetrafluorobenzene from Sigma-Aldrich , accessed on April 22, 2017 ( PDF ).
  4. a b data sheet 1,2,3,5-tetrafluorobenzene from Sigma-Aldrich , accessed on April 22, 2017 ( PDF ).