Iodonitrobenzenes

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Iodonitrobenzenes
Surname 2-iodonitrobenzene 3-iodonitrobenzene 4-iodonitrobenzene
other names o -iodonitrobenzene m -iodonitrobenzene p -iodonitrobenzene
Structural formula 2-iodonitrobenzene 3-iodonitrobenzene 4-iodonitrobenzene
CAS number 609-73-4 645-00-1 636-98-6
PubChem 69115 12574 12495
Molecular formula C 6 H 4 INO 2
Molar mass 249.01 g mol −1
Physical state firmly
Melting point 49-51 ° C 35-38 ° C 171-173 ° C
boiling point 288-289 ° C 279-280 ° C 288-290 ° C
GHS
labeling
07 - Warning
Caution
02 - Highly / extremely flammable 07 - Warning
danger
07 - Warning
Caution
H and P phrases 302-312-315-319-332-335 228-302-312-315-319-332-335 302-312-315-319-332-335
no EUH phrases no EUH phrases no EUH phrases
261-280-305 + 351 + 338 210-261-280-305 + 351 + 338 261-280-305 + 351 + 338

The iodonitrobenzenes form a group of substances in chemistry that are derived from both nitrobenzene and iodobenzene . The structure consists of a benzene ring with attached nitro group  (–NO 2 ) and iodine  (–I) as substituents . Their different arrangement results in three constitutional isomers with the empirical formula C 6 H 4 INO 2 .

properties

The p -iodonitrobenzene, which has the highest symmetry, has the highest melting point.

Individual evidence

  1. a b c d e f Alfa-Aesar catalog 2008/09, p. 1153.
  2. Data sheet 1-Iodo-2-nitrobenzene from Sigma-Aldrich , accessed on May 3, 2011 ( PDF ).
  3. Data sheet 1-Iodo-3-nitrobenzene from Sigma-Aldrich , accessed on May 3, 2011 ( PDF ).
  4. Data sheet 1-Iodo-4-nitrobenzene from Sigma-Aldrich , accessed on May 3, 2011 ( PDF ).