Selenocarbonyl compounds
Selenocarbonyl compounds are carbonyl compounds in which the oxygen atom of a carbonyl group has been replaced by a selenium atom. Selenoaldehydes are the selenium analogues of aldehydes and selenoketones are the selenium analogues of ketones . Selenoamides are the selenium analogues of amides , selenoureas are selenium analogues of ureas .
synthesis
Carbonyl compounds are converted to selenocarbonyl compounds by reaction with Woollins' reagent . Alternatively, hydrogen selenide or P 4 Se 10 can also be used to introduce selenium.
See also
Individual evidence
- ^ Richard B. Silverman: Selenium analogs of aldehydes and ketones. In: Organic Selenium Compounds: Their Chemistry and Biology. Edited by Daniel L. Klayman and Wolfgang HH Günther, John Wiley & Sons, New York, 1973, pages 245-262.
- ↑ Robert J. Shine: Selenium analogs of carboxylic acids, Nitrogen derivatives of selenocarboxylic acids. In: Organic Selenium Compounds: Their Chemistry and Biology. Edited by Daniel L. Klayman and Wolfgang HH Günther, John Wiley & Sons, New York, 1973, pages 272-303.