3,4-epoxycyclohexanecarboxylate methyl ester
| Structural formula | ||||||||||
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| Complex mixture of stereoisomers - structural formula without stereochemistry | ||||||||||
| General | ||||||||||
| Surname | 3,4-epoxycyclohexanecarboxylate methyl ester | |||||||||
| other names |
Methyl 7-oxabicyclo [4.1.0] heptane-3-carboxylate |
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| Molecular formula | C 8 H 12 O 3 | |||||||||
| Brief description |
colorless liquid |
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| External identifiers / databases | ||||||||||
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| properties | ||||||||||
| Molar mass | 156.18 g mol −1 | |||||||||
| boiling point |
109.5-110.5 ° C (17 mmHg ) |
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| Refractive index |
1.4625 |
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| safety instructions | ||||||||||
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| As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C | ||||||||||
3,4-Epoxycyclohexanecarboxylate methyl ester is a cycloaliphatic epoxide that is added as a monovalent monomer to other monomers in the manufacture of crosslinked epoxy resins . 3,4-epoxycyclohexanecarboxylate methyl ester would itself give a linear polymer in a homopolymerization .
Manufacturing
3,4-Epoxycyclohexanecarboxylate methyl ester is prepared by epoxidizing 4-cyclohexenecarboxylate methyl ester with peracid .
properties
3,4-Epoxycyclohexanecarboxylate methyl ester has a viscosity of 6 mPa.s.
Individual evidence
- ↑ James V. Crivello, Ulrike Varlemann: Mechanistic study of the reactivity of 3,4-epoxycyclohexylmethyl 3 ′, 4′-epoxycyclohexanecarboxylate in photoinitiated cationic polymerizations . In: Journal of Polymer Science Part A: Polymer Chemistry . 33, No. 14, October 1995, pp. 2473-2486. doi : 10.1002 / pola.1995.080331421 .
- ↑ a b NORMAN A. NELSON, George A. Mortimer: bicyclo [3.1.0] hexane Derivatives. I. Synthesis of Bicyclo [3.1.0] -2-hexanone and Methyl Bicyclo [3.1.0] hexane-1-carboxylate . In: The Journal of Organic Chemistry . 22, No. 10, October 1957, pp. 1146-1153. doi : 10.1021 / jo01361a003 .
- ↑ This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
- ↑ a b c Ha Q. Pham, Maurice J. Marks: Epoxy Resins . In: Ullmann's Encyclopedia of Industrial Chemistry . September. doi : 10.1002 / 14356007.a09_547.pub2 .
- ↑ Patent US6201070 : METHOD FOR ENHANCING THE TOUGHNESS OF CYCLOALIPHATIC EPOXIDE-BASED COATINGS. Published on March 13, 2001 , inventor: Naofumi Kumabe.