Barium soap

from Wikipedia, the free encyclopedia
Barium salts of individual fatty acids (examples)
Oelic Acid Barium Salt Structural Formula V.3.svg
Barium oleate, the barium salt of oleic acid .
Palmitic Acid Barium Salt Structural Formula V.2.svg
Barium palmitate, the barium salt of palmitic acid .
Stearic Acid Barium Salt Structural Formula V.2.svg
Barium stearate , the barium salt of stearic acid .

Barium soap is a collective name for barium salts of individual fatty acids or - more often - mixtures of barium salts of several fatty acids.

Manufacturing

The saponification of natural fats and oils with barium hydroxide provides mixtures of barium salts of fatty acids and glycerine . The proportions of the individual fatty acid anions in the mixture of barium salts depends on the nature and provenance of the triglyceride used as the raw material . A chemically largely uniform barium soap can be obtained by reacting a pure fatty acid with a stoichiometric amount of barium oxide . Examples of such barium soaps are:

  • Barium oleate, the barium salt of oleic acid .
  • Barium palmitate, the barium salt of palmitic acid (hexadecanoic acid).
  • Barium stearate , the barium salt of stearic acid (octadecanoic acid), white, crystalline mass, insoluble in water and alcohol (ethanol).

use

Barium soaps are used as a thickener in mineral oil- based lubricants and lubricants , as a stabilizer for PVC and in water-repellent preparations.

More soaps

Individual evidence

  1. a b Otto-Albrecht Neumüller (Ed.): Römpps Chemie-Lexikon. Volume 1: A-Cl. 8th revised and expanded edition. Franckh'sche Verlagshandlung, Stuttgart 1979, ISBN 3-440-04511-0 , p. 367.