Cerium (IV) perchlorate
Structural formula | ||||||||||||||||
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General | ||||||||||||||||
Surname | Cerium (IV) perchlorate | |||||||||||||||
Molecular formula | Ce (ClO 4 ) 4 | |||||||||||||||
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properties | ||||||||||||||||
Molar mass | 537.92 g mol −1 | |||||||||||||||
density |
1.556 g cm −3 (25 ° C) |
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safety instructions | ||||||||||||||||
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As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . |
Cerium (IV) perchlorate is an inorganic chemical compound of cerium from the group of perchlorates .
use
Cerium (IV) perchlorate is used as a catalyst in organic chemistry (very high redox potential at Ce 4+ / Ce 3+ of +1.87 V in 8 M HClO 4 ), for the determination of strontium and for cerimetry .
Individual evidence
- ↑ Data sheet Cerium (IV) perchlorate solution, ~ 0.5 N in perchloric acid, 99.99% from Sigma-Aldrich , accessed on November 4, 2016 ( PDF ).
- ↑ This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
- ↑ KA Gschneidner, Jr., J.-CG Bünzli and VK Pecharsky: Handbook on the Physics and Chemistry of Rare Earths . Elsevier, 2006, ISBN 978-0-08-046672-9 , pp. 306 ( limited preview in Google Book search).
- ^ Philip L. Fuchs, André B. Charette, Tomislav Rovis, Jeffrey W. Bode: Essential Reagents for Organic Synthesis . John Wiley & Sons, 2016, ISBN 978-1-119-27983-9 , pp. 80 ( limited preview in Google Book search).
- ↑ WJ Mijs, CRHI de Jonge: Organic Synthesis by oxidation with metal compounds . Springer Science & Business Media, 2013, ISBN 978-1-4613-2109-5 , pp. 601 ( limited preview in Google Book search).
- ↑ E. Gagliardi, E. Wolf: Determination of strontium with cerium (IV) perchlorate. In: Mikrochimica Acta. 51, 1963, p. 578, doi : 10.1007 / BF01217587 .
- ^ PH List, L. Hörhammer: General part. Drug groups I . Springer-Verlag, 2013, ISBN 978-3-642-47985-4 , pp. 301 ( limited preview in Google Book search).