Cerium (IV) perchlorate

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Structural formula
Cerion 4th Perchlorate ion
General
Surname Cerium (IV) perchlorate
Molecular formula Ce (ClO 4 ) 4
External identifiers / databases
CAS number 14338-93-3
EC number 238-290-8
ECHA InfoCard 100,034,794
PubChem 167073
Wikidata Q27699277
properties
Molar mass 537.92 g mol −1
density

1.556 g cm −3 (25 ° C)

safety instructions
GHS hazard labeling
no classification available
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Cerium (IV) perchlorate is an inorganic chemical compound of cerium from the group of perchlorates .

use

Cerium (IV) perchlorate is used as a catalyst in organic chemistry (very high redox potential at Ce 4+ / Ce 3+ of +1.87 V in 8 M HClO 4 ), for the determination of strontium and for cerimetry .

Individual evidence

  1. Data sheet Cerium (IV) perchlorate solution, ~ 0.5 N in perchloric acid, 99.99% from Sigma-Aldrich , accessed on November 4, 2016 ( PDF ).
  2. This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
  3. KA Gschneidner, Jr., J.-CG Bünzli and VK Pecharsky: Handbook on the Physics and Chemistry of Rare Earths . Elsevier, 2006, ISBN 978-0-08-046672-9 , pp. 306 ( limited preview in Google Book search).
  4. ^ Philip L. Fuchs, André B. Charette, Tomislav Rovis, Jeffrey W. Bode: Essential Reagents for Organic Synthesis . John Wiley & Sons, 2016, ISBN 978-1-119-27983-9 , pp. 80 ( limited preview in Google Book search).
  5. WJ Mijs, CRHI de Jonge: Organic Synthesis by oxidation with metal compounds . Springer Science & Business Media, 2013, ISBN 978-1-4613-2109-5 , pp. 601 ( limited preview in Google Book search).
  6. E. Gagliardi, E. Wolf: Determination of strontium with cerium (IV) perchlorate. In: Mikrochimica Acta. 51, 1963, p. 578, doi : 10.1007 / BF01217587 .
  7. ^ PH List, L. Hörhammer: General part. Drug groups I . Springer-Verlag, 2013, ISBN 978-3-642-47985-4 , pp. 301 ( limited preview in Google Book search).