Gold (V) fluoride

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Structural formula
Structural formula of gold (V) fluoride
General
Surname Gold (V) fluoride
other names

Gold pentafluoride

Molecular formula On 5
Brief description

red solid

External identifiers / databases
CAS number 57542-85-5
Wikidata Q3239166
properties
Molar mass 291.96 g mol −1
Physical state

firmly

Sublimation point

80 ° C

safety instructions
GHS hazard labeling
no classification available
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Gold (V) fluoride is an inorganic chemical compound of gold from the group of fluorides .

Extraction and presentation

Gold (V) fluoride can be obtained by thermal decomposition of dioxygenyl hexafluoroaurate O 2 AuF 6 at 200 ° C or KrF [AuF 6 ] at 60 ° C.

properties

Gold (V) fluoride is a red diamagnetic solid that decomposes at 200 ° C into gold (III) fluoride and fluorine . In the solid state, the molecules exist as dimers. Dimers and trimers are present in the gas phase. Gold (V) fluoride is a strong Lewis acid .

Individual evidence

  1. a b WebElements: Gold pentafluoride
  2. ^ A b c Erwin Riedel, Christoph Janiak: Inorganische Chemie . Walter de Gruyter, 2011, ISBN 3-11-022566-2 , p. 760 ( limited preview in Google Book search).
  3. This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
  4. ^ A b Antonio Laguna: Modern Supramolecular Gold Chemistry: Gold-Metal Interactions and Applications . John Wiley & Sons, 2008, ISBN 3-527-62376-0 , pp. 49 ( limited preview in Google Book search).