Witches

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Hexenes (emphasis on the second syllable) are chemical compounds from the group of alkenes with the empirical formula C 6 H 12 . The root Hex indicates the six carbon atoms , the ending en indicates the double bond between two of the carbon atoms. There are various isomers which differ in the position of the double bond and the presence or location of a branch in the carbon chain. The most commonly used compound in industry is 1-hexene , which is e.g. B. as a comonomer in the production ofPolyethene is used.

Isomers

Without branching

With simple branching

With double branching

properties

Surname Structural formula CAS number Melting point
in ° C
Boiling point
in ° C
Density
in g / cm 3
Refractive index
(589 nm)
1 witches Hex-1-ene 200.svg 592-41-6 −139.76 63.48 0.6685 (25 ° C) 1.3852 (25 ° C)
( E ) -2-hexene (E) -hex-2-ene 200.svg 4050-45-7 −133 67.9 0.6733 (25 ° C) 1.3936 (20 ° C)
( Z ) -2-hexene (Z) -hex-2-ene 200.svg 7688-21-3 −141.11 68.8 0.6824 (25 ° C) 1.3979 (20 ° C)
( E ) -3-hexen (E) -hex-3-ene 200.svg 13269-52-8 −115.4 67.1 0.6772 (20 ° C) 1.3943 (20 ° C)
( Z ) -3-hexene (Z) -hex-3-ene 200.svg 7642-09-3 −137.8 66.4 0.6778 (20 ° C) 1.3947 (20 ° C)
2-methyl-1-pentene 2-methylpent-1-ene 200.svg 763-29-1 −135.7 62.1 0.6799 (20 ° C) 1.3920 (20 ° C)
2-methyl-2-pentene 2-methylpent-2-ene 200.svg 625-27-4 −135 67.3 0.6863 (20 ° C) 1.4004 (20 ° C)
3-methyl-1-pentene 3-methylpent-1-ene 200.svg 760-20-3 −153 54.2 0.6675 (20 ° C) 1.3841 (20 ° C)
  • ( R ) -3-methyl-1-pentene
(R) -3-methylpent-1-ene 200.svg 39914-58-4
  • ( S ) -3-methyl-1-pentene
(S) -3-methylpent-1-ene 200.svg 5026-95-9
( E ) -3-methyl-2-pentene (E) -3-methylpent-2-ene 200.svg 616-12-6 −138.5 70.4 0.6930 (25 ° C) 1.4045 (20 ° C)
( Z ) -3-methyl-2-pentene (Z) -3-methylpent-2-ene 200.svg 922-62-3 −134.8 67.7 0.6886 (25 ° C) 1.4016 (20 ° C)
4-methyl-1-pentene 4-methylpent-1-ene 200.svg 691-37-2 −153.6 53.9 0.6642 (20 ° C) 1.3828 (20 ° C)
( E ) -4-methyl-2-pentene (E) -4-methylpent-2-ene 200.svg 674-76-0 −140.8 58.6 0.6686 (20 ° C) 1.3889 (20 ° C)
( Z ) -4-methyl-2-pentene (Z) -4-methylpent-2-ene 200.svg 691-38-3 −134.8 56.3 0.6690 (20 ° C) 1.3800 (20 ° C)
3-methylidene pentane 3-methylenepentane 200.svg 760-21-4 −131.5 64.7 0.6894 (20 ° C) 1.3969 (20 ° C)
2,3-dimethyl-1-butene 2,3-dimethylbut-1-ene 200.svg 563-78-0 −157.3 55.6 0.6803 (20 ° C) 1.3995 (20 ° C)
2,3-dimethyl-2-butene 2,3-dimethylbut-2-ene 200.svg 563-79-1 0-74.19 73.3 0.7080 (20 ° C) 1.4122 (20 ° C)
3,3-dimethyl-1-butene 3,3-dimethylbut-1-ene 200.svg 558-37-2 −115.2 41.2 0.6529 (20 ° C) 1.3763 ​​(20 ° C)

Web links

Commons : Hexene  - Collection of pictures, videos and audio files

Individual evidence

  1. a b c d David R. Lide (Ed.): CRC Handbook of Chemistry and Physics . 90th edition. (Internet version: 2010), CRC Press / Taylor and Francis, Boca Raton, FL, Physical Constants of Organic Compounds, pp. 3-1 - 3-523.