Isobenzofuran

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Structural formula
Structural formula of isobenzofuran
General
Surname Isobenzofuran
other names
  • Benzo [ c ] furan
  • 2-oxa-2 H -isoindole
Molecular formula C 8 H 6 O
External identifiers / databases
CAS number 270-75-7
PubChem 11378474
Wikidata Q761117
properties
Molar mass 118.13 g mol −1
safety instructions
GHS hazard labeling
no classification available
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Isobenzofuran is a chemical compound from the group of bicyclic heteroaromatics and is the oxygen analog of isoindole . It is made up of a furan ring and a fused benzene ring. It is isomeric to benzofuran .

Appearance and properties

Preparation of isobenzofuran from benzo [b] -7-oxa-bicyclo [2.2.1] hept-2-en

Isobenzofuran is much more unstable than benzofuran due to its electronic configuration. It can be formed by vacuum pyrolysis of benzo [ b ] -7-oxa-bicyclo [2.2.1] hept-2-ene and polymerizes rapidly even at low temperatures. The compound is the basic structure of some other natural and man-made organic compounds, of which the 1,3- diaryl- substituted (such as 1,3-diphenylisobenzofuran ) are the most stable.

Individual evidence

  1. This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
  2. ^ Theophil Eicher, Siegfried Hauptmann, Andreas Speicher: The Chemistry of Heterocycles: Structures, Reactions, Synthesis, and Applications . John Wiley & Sons, 2013, ISBN 978-3-527-66987-5 , pp. 84 ( limited preview in Google Book search).
  3. John A. Joule, Keith Mills: Heterocyclic Chemistry . John Wiley & Sons, 2010, ISBN 0-470-68597-2 , pp. 451 ( limited preview in Google Book search).