Norbert W. Mitzel

from Wikipedia, the free encyclopedia
Norbert W. Mitzel (2017)

Norbert Mitzel (born July 14, 1966 in Augsburg ) is a German chemist and professor of inorganic chemistry and structural chemistry .

Life

Norbert Werner Mitzel studied chemistry from 1985 to 1991 at the Technical University of Munich and passed his diploma exam in 1991. In 1993 he did his doctorate with Hubert Schmidbaur on "Volatile Silylamines, Hydrazines and Hydroxylamines". He worked with David WH Rankin at the University of Edinburgh for two years . He completed his habilitation in 2000 at the Technical University of Munich . In 2001 he was appointed to the Technical University of Berlin , followed by an appointment to the Westfälische Wilhelms-Universität Münster in 2002 and, in 2007, an appointment to the University of Bielefeld for a chair in inorganic and structural chemistry .

plant

He is the author of more than 300 scientific articles. He is a preparative inorganic chemist , mainly active in the field of main group chemistry. He dealt with the preparative chemistry of the element silicon (volatile hydridosilanes, silicon as Lewis acid, hypercoordinated compounds), the element nitrogen (hydrazines and hydroxylamines), the element phosphorus ( ylides , phosphoranes ), the elements aluminum , gallium and Indium ( Lewis acid chemistry), the early transition metals and the lanthanoids .

Norbert Mitzel is also a structural chemist . He is particularly dedicated to clarifying the structure of small molecules in different phases. He runs one of the few laboratories in the world in which gas- phase structures are elucidated using gas-phase electron diffraction . Solid structures of substances that are liquid or gaseous at room temperature are examined using in-situ crystallization and X-ray diffraction , structures in solution using various methods of NMR spectroscopy .

Awards

Fonts (selection)

  • London dispersion-driven hetero-aryl-aryl interactions in 1,2-diaryldisilanes , M. Linnemannstöns, J. Schwabedissen, AA Schultz, B. Neumann, H.-G. Stammler, RJF Berger, NW Mitzel, Chem. Commun. 2020 , 56, 2252-2255.
  • Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates , M. Reichel, B. Krumm, Y. Vishnevskiy, S. Blomeyer, J. Schwabedissen, H.-G. Stammler, K. Karaghiosoff, NW Mitzel, Angew. Chem. Int. Ed. 2019 , 58 , 18557-1856.
  • A Neutral Methylene-linked Tin / Phosphorus Frustrated Lewis Pair, P. Holtkamp, ​​F. Friedrich, E. Stratmann, A. Mix, B. Neumann, H.-G. Stammler, Norbert W. Mitzel, Angew. Chem. Int. Ed. 2019 , 58 , 5114-5118.
  • Bidentate Boron-Lewis Acids - Selectivity in Host-Guest Complex Formati on, P. Niermeier, S. Blomeyer, YKJ Bejaoui, L. Beckmann, B. Neumann, H.-G. Stammler, NW Mitzel, Angew. Chem. Int. Ed. 2019 , 58 , 1965-1969.
  • Tetranitromethane - a nightmare of molecular flexibility in the gaseous and solid state, Yu. V. Vishnevskiy, DS Tikhonov, J. Schwabedissen, H.-G. Stammler, R. Moll, B. Krumm, TM Klapötke, NW Mitzel, Angew. Chem. Int. Ed. 2017 , 56 , 9619-9623.
  • From bidentate gallium Lewis acids to supramolecular complexes, J. Horstmann, M. Hyseni, A. Mix, B. Neumann, H.-G. Stammler, NW Mitzel, Angew. Chem. Int. Ed. 2017 , 56 , 6107-6111.
  • Intramolecular π-π Interactions in Flexibly Linked Partially Fluorinated Bisarenes in the Gas Phase , S. Blomeyer, M. Linnemannstöns, JH Nissen, J. Paulus, B. Neumann, H.-G. Stammler, NW Mitzel, Angew. Chem. Int. Ed. 2017 , 56 , 13259-13263.
  • Tris (perfluorotolyl) borane-A Boron Lewis Superacid, LA Körte, J. Schwabedissen, M. Soffner, S. Blomeyer, C. Reuter, Yu. Vishnevskiy, B. Neumann, H. - G. Stammler, NW Mitzel, Angew. Chem. Int. Ed. 2017 , 56, 8578-8582.
  • Intramolecular cooperativity in frustrated Lewis pairs, LA Körte, S. Blomeyer, S. Heidemeyer, A. Mix, B. Neumann, NW Mitzel, Chem. Commun. 2016 , 52 , 9949-9952.
  • Gas electron diffraction of increased performance through optimization of nozzle, system design and digital control , CG Reuter, Yu. V. Vishnevskiy, S. Blomeyer, NW Mitzel, Z. Naturforsch. 2016 , 71b , 1-13.
  • A Neutral Silicon / Phosphorus Frustrated Lewis Pair, B. Waerder, M. Pieper, LA Körte, TA Kinder, A. Mix, B. Neumann, H.-G. Stammler, NW Mitzel, Angew. Chem. Int. Ed. 2015 , 54 , 13416-13419.
  • Trimethylaluminum: Bonding by Charge and Current Topology, H.-G. Stammler, S. Blomeyer, RJF Berger, NW Mitzel, Angew. Chem. Int. Ed. 2015 , 54 , 13816-13820.
  • Solid state structure of a Li / F carbenoid: Pentafluoroethyllithium , B. Waerder, S. Steinhauer, B. Neumann, H.-G. Stammler, A. Mix, Yu. V. Vishnevskiy, B. Hoge, NW Mitzel, Angew. Chem. Int. Ed. 2014 , 53 , 11640-11644.
  • Structural Methods in Molecular Inorganic Chemistry, (Inorganic Chemistry: A Textbook Series) , DWH Rankin, NW Mitzel, CA Morrison, 1st edition, John Wiley & Sons, Chichester, February 2013, ISBN 978-0-470-97279-3 (hardcover ) and ISBN 978-0-470-97278-6 (soft cover).
  • Mechanism of Host-Guest Complex Formation and Identification of Intermediates through NMR Titration and Diffusion NMR Spectroscopy, J.-H. Lamm, P. Niermeier, A. Mix, J. Chmiel, B. Neumann, H.-G. Stammler, NW Mitzel, Angew. Chem. Int. Ed. 2014 , 53 , 7938-7942.
  • Lewis Base Induced Reductions in Organolanthanide Chemistry, D. Bojer, A. Venugopal, B. Neumann, H.-G. Stammler, NW Mitzel, Angew. Chem. Int. Ed. 2010 , 49, 2611-2614.
  • On the Molecular and Electronic Structures of AsP 3 and P 4 , BM Cossairt, CC Cummins, AR Head, DL Lichtenberger, RJF Berger, SA Hayes, NW Mitzel, G. Wu, J. Am. Chem. Soc. 2010 , 132, 8459-8465.
  • Two diamino-substituted lithiocarbanions in one molecule , I. Kamps, A. Mix, RJF Berger, B. Neumann, H.-G. Stammler, NW Mitzel, Chem. Comm. 2009 , 5558-5560.
  • Carbanions with two N substituents: Nucleophilic acyl-group-transfer reagents, D. Bojer, I. Kamps, X. Tian, ​​A. Hepp, T. Pape, R. Fröhlich, NW Mitzel, Angew. Chem. Int. Ed. , 2007 , 46 , 4176-4179.
  • Oxygenation of simple zinc alkyls: Surprising dependence of product distributions on the alkyl substituents and the presence of water , S. Jana, RJF Berger, R. Fröhlich, NW Mitzel, Inorg. Chem.  2007 , 46, 4293-4297.
  • First mixed hydrazide / hydroxylamide metal aggregates , S. Jana, R. Fröhlich, RJF Berger, NW Mitzel, Chem. Commun. 2006 , 3993-3995.
  • Hypercoordinate silicon in the monomeric (F 3 C) F 2 SiONMe 2 - a new model for the α-effect in the solid state and the gas phase, NW Mitzel, K. Vojinović, R. Fröhlich, T. Foerster, DWH Rankin, J. Am. Chem. Soc . 2005 , 127 , 1370-13713.
  • Luminescence Phenomena and Solid State Structures of Trimethyl- and Triethylgallium, NW Mitzel, C. Lustig, RJF Berger, N. Runeberg, Angew. Chem. Int. Ed. 2002 , 41 , 2519-2523.
  • Two different reaction modes of the highly flexible ligand bis (hydroxylamine) [HON (Me)] 2 CH 2 with trimethylaluminum and -gallium, NW Mitzel, C. Lustig, Angew. Chem. Int. Ed. , 2001 , 113 , 4390-4392.
  • (N, N-Dimethylaminoxy) trifluorosilane: Strong, Dipole Moment Driven Changes in the Molecular Geometry Studied by Experiment and Theory in Solid, Gas and Solution Phases, NW Mitzel, U. Losehand, A. Wu, D. Cremer, DWH Rankin, J. Am. Chem. Soc., 2000 , 122 , 4471-4482.
  • β-Donor Interactions of Exceptional Strength in N, N-Dimethylhydroxylaminochlorosilane, ClH 2 SiONMe 2 , NW Mitzel, U. Losehand, J. Am. Chem. Soc. 1998 , 120 , 7320-7327.
  • Differences Between the Gas-Phase and Solid-State Structures of the Simplest Phosphonium Ylid, Me 3 P = CH 2 , NW Mitzel, DH Brown, S. Parsons, PT Brain, CR Pulham, DWH Rankin, Angew. Chem., Int. Ed. Engl. 1998 , 37 , 1670-1672.
  • β-Donor Bonds in Compounds Containing SiON Fragments , NW Mitzel, U. Losehand, Angew. Chem., Int. Ed. Engl. 1997 , 36 , 2807-2809.
  • The Crystal Structure of Aziridines , NW Mitzel, J. Riede, C. Kiener, Angew. Chem., Int. Ed. Engl. 1997 , 36, 2215-2216.
  • β-Donor Bonds in SiON Units: An Inherent Structure-Determining Property Leading to (4 + 4) -Coordination in Tetrakis- (N, N-dimethylhydroxylamido) silane , NW Mitzel, AJ Blake, DWH Rankin, J. Am. Chem. Soc. 1997 , 119 , 4143-4148.
  • Low Symmetry in P (NR 2 ) 3 Skeletons and Related Fragments: An Inherent Phenomenon , NW Mitzel, BA Smart, K.-H. Dreihäupl, DWH Rankin, H. Schmidbaur, J. Am. Chem. Soc. 1996 , 118 , 12673-12682.

Web links

Individual evidence

  1. ^ NW Mitzel: Professor Hubert Schmidbaur on his 70th birthday. In: Journal of Nature Research B . 59, 2004, pp. 1181–1184 (curriculum vitae in the dedication volume for his 70th birthday)
personal data
SURNAME Mitzel, Norbert W.
ALTERNATIVE NAMES Mitzel, Norbert Werner
BRIEF DESCRIPTION German chemist
DATE OF BIRTH July 14, 1966
PLACE OF BIRTH augsburg