Palladium (II) nitrate

Structural formula
General
Surname	Palladium (II) nitrate
other names	Palladium nitrate
Molecular formula	Pd (NO 3 ) 2
Brief description	brown solid (hydrate)
External identifiers / databases
EC number	233-265-8
ECHA InfoCard	100.030.228
PubChem	24932
Wikidata	Q416480
properties
Molar mass	230.43 g mol −1
Physical state	firmly
solubility	bad in water, good in dilute nitric acid
safety instructions
H and P phrases	H: 272-315-319-335
	P: 220-261-305 + 351 + 338
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Palladium (II) nitrate is the palladium salt of nitric acid .

Extraction and presentation

Palladium (II) nitrate is obtained by dissolving palladium in hot, concentrated nitric acid.

{\ displaystyle \ mathrm {3 \ Pd + 8 \ HNO_ {3} \ longrightarrow 3 \ Pd (NO_ {3}) _ {2} +2 \ NO + 4 \ H_ {2} O}}

properties

Physical Properties

Palladium (II) nitrate is a red-brown powder at room temperature. It is sparingly soluble in water and forms a cloudy solution as a result of hydrolysis . It is soluble in dilute nitric acid.

Chemical properties

Palladium (II) nitrate decomposes when heated. It hydrolyzes in excess water, forming a brown, basic salt. It has a strong oxidizing effect, since both the Pd ²⁺ ion and the nitrate ion NO ₃^{- are} oxidizing. Crystalline palladium (II) oxide is formed by precipitation with sodium hydroxide solution .

use

Palladium (II) nitrate is suitable for the production of pure palladium and palladium (II) sulfate . .

Individual evidence

↑ ^a ^b Datasheet Palladium (II) nitrate hydrate (PDF) from Strem, accessed on December 25, 2012.
↑ ^a ^b Datasheet Palladium (II) nitrate hydrate from Sigma-Aldrich , accessed on April 16, 2011 ( PDF ).
↑ ^a ^b Cotton, Simon; The Chemistry of Precious Metals; Springer 1997.
↑ Martin Schreyer: Contributions to the chemistry of transition metal oxides. Dissertation, Uni Bonn, 2001, urn : nbn: de: hbz: 5n-00046 .
↑ Georg Brauer (ed.) U. a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume III, Ferdinand Enke, Stuttgart 1981, ISBN 3-432-87823-0 , p. 1731.

[strem-1] Datasheet Palladium (II) nitrate hydrate (PDF) from Strem, accessed on December 25, 2012.

[Sigma-2] Datasheet Palladium (II) nitrate hydrate from Sigma-Aldrich , accessed on April 16, 2011 ( PDF ).

[Cotton-3] Cotton, Simon; The Chemistry of Precious Metals; Springer 1997.

[4] Martin Schreyer: Contributions to the chemistry of transition metal oxides. Dissertation, Uni Bonn, 2001, urn : nbn: de: hbz: 5n-00046 .

[brauer-5] Georg Brauer (ed.) U. a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume III, Ferdinand Enke, Stuttgart 1981, ISBN 3-432-87823-0 , p. 1731.