Palladium (II, IV) fluoride

Crystal structure
__ Pd 2 + / 4 +      __ F -
General
Surname	Palladium (II, IV) fluoride
other names	Palladium trifluoride Palladium (II) hexafluoropalladate (IV)
Ratio formula	PdF 3
External identifiers / databases
CAS number 12021-58-8 Wikidata Q29588
properties
Molar mass	163.42 g mol −1
safety instructions
GHS hazard labeling no classification available
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Palladium (II, IV) fluoride is an inorganic chemical compound of palladium from the group of fluorides .

Extraction and presentation

Palladium (II, IV) fluoride can be obtained by reaction of palladium with chlorine to form palladium (II, IV) chloride and the subsequent displacement of the chlorine by fluorine at 200 to 250 ° C.

${\displaystyle \mathrm {2\ Pd+3\ F_{2}\longrightarrow 2\ PdF_{3}} }$

properties

Palladium (II, IV) fluoride is a black, rhombic solid that is hydrolyzed by water. It is soluble in acids and alkalis and is reduced to metal by hydrogen at room temperature under the appearance of a fire. It has a rhombohedral distorted crystal structure of the rhenium (VI) oxide type.

Individual evidence

1. ↑ This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
2. ↑ G. Singh: Chemistry Of Lanthanides And Actinides . Discovery Publishing House, 2007, ISBN 81-8356-241-8 , pp. 237 ( limited preview in Google Book search).
3. ↑ Georg Brauer (Ed.), With the collaboration of Marianne Baudler a . a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume I, Ferdinand Enke, Stuttgart 1975, ISBN 3-432-02328-6 , p. 263.
4. ↑ Ralf Alsfasser, Erwin Riedel, HJ Meyer: Moderne Anorganische Chemie . Walter de Gruyter, 2007, ISBN 3-11-019060-5 , p. 345 ( limited preview in Google Book search).