Rhenocene

Structural formula
	Ecliptic conformation
General
Surname	Rhenocene
other names	Bis (cyclopentadienyl) rhenium; Cp2Re;
Molecular formula	C 10 H 10 Re
External identifiers / databases
PubChem	124321
Wikidata	Q43685233
properties
Molar mass	316.39 g mol −1
safety instructions
GHS hazard labeling ; no classification available
GHS hazard labeling ; no classification available
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Rhenocene (named after IUPAC : bis (η ⁵ -cyclopentadienyl) rhenium (II) ) with the semi- structural formula [Re (C ₅ H ₅ ) ₂ ] or also [Re (Cp) ₂ ] , is a chemical compound of the rhenium group the metallocenes .

Extraction and presentation

Rhenocene can be produced, isolated and investigated by photolysis of Re (C ₅ H ₅ ) ₂ H in a nitrogen and argon matrix at 12 K. A pentamethyl derivative and rhenocene hydride can be isolated above this temperature.

properties

At very low temperatures, the rhenocene complex is monomeric and has a sandwich structure .

use

Rhenocene complexes are examined for their antitumor activity.

Individual evidence

↑ This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
↑ Entry on sandwich compounds . In: IUPAC Compendium of Chemical Terminology (the “Gold Book”) . doi : 10.1351 / goldbook.S05468 .
↑ ^a ^b Jeremy N. Hill, Robin N. Perutz, A. Denise Rooney: Laser-Induced Fluorescence of Rhenocene in Low-Temperature Matrixes: Selective Excitation and Emission . In: J. Phys. Chem. Band 99 , no. 2 , 1995, p. 531-537 , doi : 10.1021 / j100002a014 .
↑ subgroup elements, lanthanides, actinides, transactinides Volume 2: transition elements, lanthanides, actinides, transactinide attachments . Walter de Gruyter GmbH & Co KG, 2016, ISBN 978-3-11-049590-4 , p. 1929 ( limited preview in Google Book Search).
^ SP Fricker: Metal Compounds in Cancer Therapy . Springer Science & Business Media, 2012, ISBN 978-94-011-1252-9 , pp. 138 ( limited preview in Google Book search).

[NV-1] This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.

[2] Entry on sandwich compounds . In: IUPAC Compendium of Chemical Terminology (the “Gold Book”) . doi : 10.1351 / goldbook.S05468 .

[JPhysChem_1995_531-3] Jeremy N. Hill, Robin N. Perutz, A. Denise Rooney: Laser-Induced Fluorescence of Rhenocene in Low-Temperature Matrixes: Selective Excitation and Emission . In: J. Phys. Chem. Band 99 , no. 2 , 1995, p. 531-537 , doi : 10.1021 / j100002a014 .

[4] subgroup elements, lanthanides, actinides, transactinides Volume 2: transition elements, lanthanides, actinides, transactinide attachments . Walter de Gruyter GmbH & Co KG, 2016, ISBN 978-3-11-049590-4 , p. 1929 ( limited preview in Google Book Search).

[S.P._Fricker-5] SP Fricker: Metal Compounds in Cancer Therapy . Springer Science & Business Media, 2012, ISBN 978-94-011-1252-9 , pp. 138 ( limited preview in Google Book search).