Tetracarbon dioxide

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Structural formula
Structural formula of tetracarbon dioxide
General
Surname Tetracarbon dioxide
other names
  • Butatriendion
  • 1,2,3-butatriene-1,4-dione
Molecular formula C 4 O 2
External identifiers / databases
CAS number 51799-35-0
PubChem 15039474
Wikidata Q3028850
properties
Molar mass 80.04 g mol −1
safety instructions
GHS hazard labeling
no classification available
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Tetracarbon dioxide is a chemical compound from the group of oxides . It is the fourth member of the series of linear carbon dioxides O (= C) n = O, which includes carbon dioxide O = C = O, ethendione O = C = C = O, carbon suboxide O = C = C = C = O and so on .

Extraction and presentation

The compound was first obtained in 1990 by Günther Maier and others through the photolysis of diazoketones in an argon matrix and is the first carbon dioxide with an even number of carbon atoms .

C4O2 by photolyse of diazoketone.png

properties

Tetracarbon dioxide likely has a triplet ground state.

Individual evidence

  1. This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
  2. ^ Günther Maier, Hans Peter Reisenauer, Heinz Balli, Willy Brandt, Rudolf Janoschek: C4O2 (1,2,3-butatriene-1,4-dione), the first carbon dioxide with an even number of carbon atoms. In: Angewandte Chemie. 102, 1990, pp. 920-923, doi : 10.1002 / anie. 19901020815 .
  3. ^ J. Buckingham: Dictionary of Organic Compounds . CRC Press, 1990, ISBN 0-412-54090-8 , pp. 1145 ( limited preview in Google Book search).