1-fluorobutane

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Structural formula
Structural formula of 1-fluorobutane
General
Surname 1-fluorobutane
other names

Butyl fluoride

Molecular formula C 4 H 9 F
External identifiers / databases
CAS number 2366-52-1
ECHA InfoCard 100.017.386
PubChem 16908
Wikidata Q57985184
properties
Molar mass 76.11 g mol −1
density

0.779 g cm −3

Melting point

−134 ° C

boiling point

31.5 ° C

solubility

very soluble in ethanol

Refractive index

1.3410 (20 ° C)

safety instructions
GHS hazard labeling
no classification available
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C

1-fluorobutane is a chemical compound from the group of aliphatic , saturated halogenated hydrocarbons .

Extraction and presentation

1-Fluorobutane can be obtained by reacting 1-bromobutane with mercury (II) fluoride or by reacting 1-butanol with 2-chloro-1,1,2-trifluoroethyl) diethylamine . The compound can also be obtained by reacting 1-bromobutane with potassium fluoride in ethylene glycol .

properties

1-fluorobutane is a liquid with a low boiling point that is very soluble in ethanol . The molecule shows a positive charge on the C 2 atom, which comes about through quantum effects.

use

1-fluorobutane can be used to etch semiconductors .

Individual evidence

  1. a b c d David R. Lide: CRC Handbook of Chemistry and Physics A Ready-reference Book of Chemical and Physical Data . CRC Press, 1995, ISBN 978-0-8493-0595-5 ( limited preview in Google Book Search).
  2. a b c I.L. Knunyants, GG Yakobson: Syntheses of Fluoroorganic Compounds . Springer Science & Business Media, 2012, ISBN 978-3-642-70207-5 , p. 4 ( limited preview in Google Book search).
  3. This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
  4. ^ Chemical Society (Great Britain): Journal of the Chemical Society . The Society, 1964, ISSN  0368-1769 , pp. 1322 ( limited preview in Google Book search).
  5. Eric V. Anslyn, Dennis A. Dougherty: Modern Physical Organic Chemistry . University Science Books, 2006, ISBN 978-1-891389-31-3 , pp. 16 ( limited preview in Google Book search).
  6. Google Patents: EP3012241A1 - High-purity 1-fluorobutane and plasma etching method - Google Patents , accessed October 30, 2018