1-pentadecanol

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Structural formula
Structural formula of 1-pentadecanol
General
Surname 1-pentadecanol
other names
  • Pentadecyl alcohol
  • Pentadecan-1-ol
Molecular formula C 15 H 32 O
Brief description

white solid

External identifiers / databases
CAS number 629-76-5
EC number 211-107-9
ECHA InfoCard 100.010.099
PubChem 12397
Wikidata Q27146999
properties
Molar mass 228.41 g mol −1
Physical state

firmly

Melting point

41-44 ° C

boiling point

269-271 ° C

solubility

practically insoluble in water

safety instructions
GHS labeling of hazardous substances
no GHS pictograms
H and P phrases H: no H-phrases
P: no P-phrases
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

1-Pentadecanol is a chemical compound from the group of linear alkanols .

Occurrence

1-Pentadecanol occurs naturally in Hymenoptera .

Extraction and presentation

1-Pentadecanol can be obtained by reacting silver palmitate with iodine .

The synthesis is also possible by reacting hexadecene at low temperature with ozone to form the corresponding ozonide , which is reduced to 1-pentadecanol with sodium borohydride .

properties

1-Pentadecanol is a white fluffy solid that is practically insoluble in water.

use

1-Pentadecanol is used as a starting material for the production of other chemical compounds (e.g. Jaspin B).

Individual evidence

  1. a b c d e f g data sheet 1-pentadecanol, 99% from Sigma-Aldrich , accessed on August 17, 2018 ( PDF ).
  2. a b Data sheet 1-Pentadecanol, 99% from AlfaAesar, accessed on August 17, 2018 ( PDF )(JavaScript required) .
  3. E. David Morgan, N. Bhushan Mandava: Handbook of Natural Pesticides Pheromono . CRC Press, 1988, ISBN 978-0-8493-3658-4 , pp. 146 ( limited preview in Google Book search).
  4. ^ Frank C. Whitmore: Organic Chemistry, Volume One Part I: Aliphatic Compounds Part II: Alicyclic Compounds . Courier Corporation, 2012, ISBN 978-0-486-60700-9 , pp. 132 ( limited preview in Google Book search).
  5. Practical Preparation of Pentadecanol and 1 Bromopentadecane from 1 Hexadecene - 《CHINESE JOURNAL OF PHARMACEUTICALS》 2000 年 05 期: Practical Preparation of Pentadecanol and 1 Bromopentadecane from 1 Hexadecene - 《CHINESE JOURNAL OF PHARMACEUTICALS accessed on May 17, 2000 August 2018.
  6. K. Venkatesan, KV Srinivasan: A novel stereoselective synthesis of pachastrissamine (jaspine B) starting from 1-pentadecanol. In: Tetrahedron: Asymmetry. 19, 2008, p. 209, doi : 10.1016 / j.tetasy.2007.12.001 .