1 H -borepine

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Structural formula
Structural formula of 1H-borepine
General
Surname 1 H -borepine
Molecular formula C 6 H 7 B
External identifiers / databases
CAS number 291-62-3
PubChem 14970100
ChemSpider 26666607
Wikidata Q23328839
properties
Molar mass 89.93 g mol −1
safety instructions
GHS hazard labeling
no classification available
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Borepine is an unsaturated heterocyclic chemical compound . It is the simplest seven-membered unsaturated boron- containing heterocycle and thus the parent compound of the borepines. 1 H -Borepin is isoelectronic with the tropylium - cation .

presentation

Borepine can be generated from the corresponding chloroborepine and tributylstannane by Cl-H exchange .

Individual evidence

  1. This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
  2. Arthur J. Ashe, Wolfram Klein, Roger Rousseau: Evaluation of the aromaticity of borepin: synthesis and properties of 1-substituted borepins. In: Organometallics. 12, 1993, p. 3225, doi: 10.1021 / om00032a051 .
  3. Arthur J. Ashe, Jeff W. Kampf, Yasuhiro Nakadaira, Jennifer M. Pace: Aromatic boron heterocycles: Generation of 1H-borepine and structure of tricarbonyl (1-phenylborepine) molybdenum . In: Angewandte Chemie . tape 104 , no. 9 , September 1, 1992, pp. 1267-1269 , doi : 10.1002 / anie.19921040937 .