FRD-903

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Structural formula
Structural formula of FRD-903
General
Surname FRD-903
other names
  • 2,3,3,3-tetrafluoro-2- (heptafluoropropoxy) propanoic acid
  • Perfluoro-2-propoxypropanoic acid
  • HFPO-DA
  • GenX
Molecular formula C 6 HF 11 O 3
External identifiers / databases
CAS number 13252-13-6
EC number 236-236-8
ECHA InfoCard 100.032.928
PubChem 114481
ChemSpider 102538
Wikidata Q29387971
properties
Molar mass 330.05 g mol −1
safety instructions
GHS labeling of hazardous substances
05 - Corrosive 07 - Warning

danger

H and P phrases H: 302-314-318
P: 261-264-280-301 + 312-305 + 351 + 338-310
Authorization procedure under REACH

Of particular concern: there are likely to be serious effects on human health and the environment

As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

FRD-903 is a chemical compound that belongs to the per- and polyfluorinated alkyl compounds . In the GenX process , the ammonium carboxylate salt - ammonium 2,3,3,3-tetrafluoro-2- (heptafluoropropoxy) propanoate - which is called FRD-902, is used as an inert processing aid and a substitute for perfluorooctanoic acid (PFOA). FRD-902 is made from hexafluoropropylene oxide.

FRD-903 is not biodegradable and is not hydrolyzed by water . It has been detected in river water, sediment and drinking water . In 2019, FRD-903, its salts and halides were added to the list of substances of very high concern for approval .

The chemical is the subject of a documentary - GenX: a Chemical Cocktail .

Individual evidence

  1. a b Entry on 2,3,3,3-tetrafluoro-2- (1,1,2,2,3,3,3, heptafluoropropoxy) propanoic acid (~ 90%) at Toronto Research Chemicals , accessed on 17. December 2018 ( PDF ).
  2. a b Entry in the SVHC list of the European Chemicals Agency , accessed on July 29, 2019.
  3. External identifiers of or database links for ammonium 2,3,3,3-tetrafluoro-2- (heptafluoropropoxy) propanoate : CAS number: 62037-80-3, EC number: 700-242-3, ECHA -InfoCard: 100.124.803 , PubChem : 51342034 , ChemSpider : 26235356 , Wikidata : Q29388239 .
  4. a b Rijksinstituut voor Volksgezondheid en Milieu : Evaluation of substances used in the GenX technology by Chemours, Dordrecht , 2016 ( PDF ).
  5. a b Cheryl Hogue: What's GenX still doing in the water downstream of a Chemours plant? In: Chemical & Engineering News . tape 96 , no. 7 , 2018 ( acs.org ).
  6. Mei Sun, Elisa Arevalo, Mark Strynar, Andrew Lindstrom, Michael Richardson, Ben Kearns, Adam Pickett, Chris Smith, Detlef RU Knappe: Legacy and Emerging Perfluoroalkyl Substances Are Important Drinking Water Contaminants in the Cape Fear River Watershed of North Carolina . In: Environmental Science & Technology Letters . tape 3 , no. 12 , 2016, p. 415-419 , doi : 10.1021 / acs.estlett.6b00398 .
  7. Cheryl Hogue: Fluoroethers taint sediments . In: Chemical & Engineering News . tape 96 , no. 15 , 2018, doi : 10.1021 / cen-09615-polcon2 .
  8. ^ GenX: a Chemical Cocktail. IMDB, accessed July 20, 2020 .
  9. ^ GenX: A Chemical Cocktail. Retrieved July 20, 2020 (American English).