Potassium metaborate

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Structural formula
Structural formula of potassium metaborate
General
Surname Potassium metaborate
other names

Potassium borate

Molecular formula KBO 2
Brief description

white solid

External identifiers / databases
CAS number
  • 13709-94-9
  • 16481-66-6 (hydrate)
EC number 237-262-2
ECHA InfoCard 100,033,860
PubChem 123325
Wikidata Q15627939
properties
Molar mass 81.91 g mol −1
Physical state

firmly

density

2.3 g cm −3

Melting point

947 ° C

boiling point

1401 ° C

safety instructions
GHS labeling of hazardous substances
07 - Warning 08 - Dangerous to health

Caution

H and P phrases H: 319-361d
P: 281-305 + 351 + 338
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Potassium metaborate is an inorganic chemical compound of potassium from the group of borates .

Extraction and presentation

Potassium metaborate can be obtained by reacting potassium carbonate with boron trioxide or boron nitride .

properties

Potassium metaborate is a white solid. It has a crystal structure with the space group R 3 c (space group no. 167) . The connection exists as a trimer . Template: room group / 167

use

Potassium metaborate is used in fracking fluids .

Individual evidence

  1. a b c David R. Lide: CRC Handbook of Chemistry and Physics A Ready-reference Book of Chemical and Physical Data . CRC Press, 1995, ISBN 0-8493-0595-0 , pp. 77 ( limited preview in Google Book search).
  2. a b c data sheet Potassium metaborate, ≥31% B 2 O 3 basis, ≥42% K 2 O basis from Sigma-Aldrich , accessed on February 21, 2019 ( PDF ).
  3. ^ William M. Haynes: CRC Handbook of Chemistry and Physics . CRC Press, 2016, ISBN 978-1-4987-5429-3 , pp. 104 ( limited preview in Google Book search).
  4. R. Blachnik: Pocket book for chemists and physicists Volume 3: Elements, inorganic compounds and materials, minerals . Springer-Verlag, 2013, ISBN 978-3-642-58842-6 , pp. 500 ( limited preview in Google Book Search).
  5. ^ RK Sharma: Chemistry Of Hydrides And Carbides . Discovery Publishing House, 2007, ISBN 978-81-8356-227-0 , pp. 314 ( limited preview in Google Book search).
  6. New Yearbook for Mineralogy, Geology and Paleontology: Treatises . E. Schweizerbart, 1940, OCLC 4669071 , p. 192 ( limited preview in Google Book search).
  7. ^ WH Zachariasen: The Crystal Structure of Potassium Metaborate, K3 (B3O6). In: The Journal of Chemical Physics. 5, 1937, p. 919, doi: 10.1063 / 1.1749962 .
  8. William A. Hart, OF Beumel, Thomas P. Whaley: The Chemistry of Lithium, Sodium, Potassium, Rubidium, Cesium and Francium Pergamon Texts in Inorganic Chemistry . Elsevier, 2013, ISBN 978-1-4831-8757-0 , pp. 449 ( limited preview in Google Book search).
  9. ^ Frank R. Spellman: Environmental Impacts of Hydraulic Fracturing . CRC Press, 2012, ISBN 978-1-4665-1467-6 , pp. 435 ( limited preview in Google Book search).