Sodium fluorosulfonate

Crystal structure
	No drawing available
Crystal system	hexagonal
Space group	P 6 3 / mmc (No. 194)
Lattice parameters	a = 5.4812 Å ; b = 5.4812 Å; c = 6.5172 Å;
General
Surname	Sodium fluorosulfonate
other names	Sodium fluorosulfate
Ratio formula	NaSO 3 F
Brief description	hygroscopic solid
External identifiers / databases
Wikidata	Q63441398
properties
Molar mass	122.05 g mol −1
Physical state	firmly
solubility	soluble in water, ethanol and acetone
safety instructions
GHS hazard labeling ; no classification available
GHS hazard labeling ; no classification available
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Natriumfluorosulfonat , NaSO ₃ F is the sodium - salt of fluorosulfonic .

Extraction and presentation

It is possible to produce sodium fluorosulfonate by reacting sodium hydroxide and fluorofluorosulfonate .

${\ displaystyle {\ ce {FSO3F + 2 NaOH -> NaSO3F + NaF + H2O + 1 / 2O2}}}$

properties

Sodium fluorosulfonate crystallizes in a hexagonal crystal system . It has the space group P 6 ₃ / mmc (space group no. 194) with the lattice parameters a = 5.4812 Å , b = 5.4812 Å and c = 6.5172 Å. The cell volume is 169.568 Å ³ . The length of the O - Na bond is 2.4004 Å and the angle of the O – Na – O bond is between 79 ° and 101 °. The distance between the sodium and fluorine is 3.1699 Å. Template: room group / 194

Individual evidence

^ ^A ^b Dale L. Perry: Handbook of Inorganic Compounds . CRC Press, 2016, ISBN 1-4398-1462-7 , pp. 378 .
↑ This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
↑ Frank B. Dudley, George H. Cady, David F. Eggers Jr .: Fluorine Fluorosulfonate . J. Am. Chem. Soc., January 1956, pp. 290–292 , doi : 10.1021 / ja01583a011 .
↑ Tomasz Michałowski, Piotr J.Leszczyński, Michał Cyrański, Łukasz Dobrzycki, Armand Budzianowski, Wojciech Grochala: The missing crystal structures of fluorosulfates of monovalent cations: M (I) SO3F, M = Na, Rb and Tl . In: Journal of Fluorine Chemistry . August 2012, p. 116–120 , doi : 10.1016 / j.jfluchem.2012.05.004 .

[Handbook_of_Inorganic_Compounds-1] A ^b Dale L. Perry: Handbook of Inorganic Compounds . CRC Press, 2016, ISBN 1-4398-1462-7 , pp. 378 .

[NV-2] This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.

[3] Frank B. Dudley, George H. Cady, David F. Eggers Jr .: Fluorine Fluorosulfonate . J. Am. Chem. Soc., January 1956, pp. 290–292 , doi : 10.1021 / ja01583a011 .

[4] Tomasz Michałowski, Piotr J.Leszczyński, Michał Cyrański, Łukasz Dobrzycki, Armand Budzianowski, Wojciech Grochala: The missing crystal structures of fluorosulfates of monovalent cations: M (I) SO3F, M = Na, Rb and Tl . In: Journal of Fluorine Chemistry . August 2012, p. 116–120 , doi : 10.1016 / j.jfluchem.2012.05.004 .