Oiticica oil

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Oiticia oil
Licania rigida fruits.jpg
Raw material plant (noun)

Licania rigida

origin

Seeds

colour

yellowish

ingredients
Oleic acid 6-18%
Linoleic acid 3.5-5%, (indefinite)
Palmitic acid 3–7%
More fatty acids α- licanic acid (42%) 58–61% (71.5%),
(5.3%) 14–17% α- eleostearic acid , 2.8% β-eleostearic acid , stearic acid 4.2-5% (12% ), (2% indeterminate; Hydroxy-OH)
properties
density 0.967-0.978 kg / l at 20 ° C
viscosity = 1100–2300 mm 2 / s at 25 ° C (permanent liquid)
Melting point 15 ° C
Iodine number (min. 135) 140–152 (180)
Saponification number 185-195
Manufacturing and Consumption
Production worldwide 14,000 tons (1981); 20,000 tons
Most important production countries Brazil

Oiticica tree

Oiticia oil is a vegetable oil that is obtained from the seeds of Licania rigida , a South American tree from the golden plum family of the genus Licania . Cacahuananche oil (Mexican oiticia oil) from Licania arborea is related to this . It has similar properties to tung oil ; it is one of the semi-drying oils.

The triglycerides of the oil are mainly composed of esters with couepic acid (α-licanic acid), a branched-chain and tri-unsaturated keto fatty acid ( keto acid ). The oil is also very heavy with a density of approx. 0.97 kg / l, it is probably one of the heaviest oils, the isano oil (Boleko oil) is even heavier. In terms of gelatinization, it behaves similarly to tung oil. At room temperature it is yellowish and musky , after a while it crystallizes and becomes whitish, sebum-like . After brief heating, it becomes permanently liquid, in this form it is also known as "Cicoil".

Oiticia oil is used for lacquers, varnishes , inks and for the production of linoleum and factice . It can also be used to treat wood.

Individual evidence

  1. a b c W. Heimann: Fette und Lipoide (Lipids). Springer, 1969, ISBN 978-3-642-46190-3 (reprint), p. 95.
  2. a b c d e Licania rigida at PlantFA Database, accessed on November 24, 2017.
  3. a b c d e f A. L. Markman, LN Andrianova, BK Kruptsov et al .: Triacylglycerols of oiticica oil. In: Chem. Nat. Compd. 16 (3), 1980, pp. 229-232, doi: 10.1007 / BF00567277 .
  4. M. Florkin, HS Mason: Comparative Biochemistry. Vol. III, Part A. Academic Press, 1962, p. 47.
  5. a b c d A. E. Rheineck, PR Sampath: Another look at oiticica oil. In: Journal of paint technology. 43 (360), 1971, pp. 89-97.
  6. a b Ullmann’s Food and Feed. Vol. 2, Wiley, 2017, ISBN 978-3-527-33990-7 , p. 714.
  7. H. Bönisch, H. Schönfeld a. a .: Processing and application of fats. Second volume. Springer, 1937, ISBN 978-3-7091-5264-5 (reprint), p. 257.
  8. a b ASTM D 601 - 87 (Reapproved 1998) Oiticica Oil (Permanently Liquid).
  9. a b Sabine Krist: Lexicon of vegetable fats and oils. 2nd edition, Springer, 2013, ISBN 978-3-7091-1004-1 , pp. 533-536.
  10. a b Information on oiticica oil. US Dept. of Agric., 1942, archive.org .
  11. Alain Karle child: Manuel des corps gras. 2. Volumes, AFCEG, TEC DOC, Paris 1992, ISBN 978-2-85206-662-5 .
  12. Frank D. Gunstone, John L. Harwood, Fred B. Padley: The Lipid Handbook. Second Edition, Chapman & Hall, 1994, 1995, ISBN 0-412-43320-6 , p. 79.
  13. James A. Duke: Handbook of Nuts. CRC Press, 2001, ISBN 0-8493-3637-6 , p. 206.
  14. E. Bames, A. Bömer: Handbuch der Lebensmittelchemie. IV Volume, Springer, 1939, ISBN 978-3-642-88819-9 (reprint), p. 505.
  15. ^ Oil and Color Chemists Association of Australia: Surface Coatings. Vol. I, Springer, 1983, ISBN 978-94-011-6942-4 , p. 27.
  16. World Surface Coatings Abstracts. Volumes 22-23, 1949, p. 214.
  17. ^ Heinz A. Hoppe: Drug Science. Volume 1: Angiosperms . 8th edition. De Gruyter, 1975, ISBN 3-11-003849-8 , p. 650.