Pentamethylbenzene

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Structural formula
Structural formula of pentamethylbenzene
General
Surname Pentamethylbenzene
Molecular formula C 11 H 16
External identifiers / databases
CAS number 700-12-9
EC number 211-837-8
ECHA InfoCard 100.010.763
PubChem 12784
Wikidata Q424944
properties
Molar mass 148.25 g mol −1
Physical state

firmly

density

0.917 g cm −3 (25 ° C)

Melting point

49-51 ° C

boiling point

231 ° C

safety instructions
GHS labeling of hazardous substances
02 - Highly / extremely flammable 07 - Warning

danger

H and P phrases H: 228-315-319-335
P: 210-261-305 + 351 + 338
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Pentamethylbenzene is a benzene substituted by five methyl groups and thus an aromatic hydrocarbon .

It is a solid with a melting point of 49-51 ° C. In comparison with the tetramethylbenzenes , this is lower than that of Durol at 79.2 ° C due to the lower symmetry . However, it is also higher than that of Isodurol at −20 ° C and Prehnitol at −6.3 ° C due to the higher degree of substitution .

It arises from the reaction of formaldehyde / HCl with xylene mixtures .

literature

Individual evidence

  1. a b c d e data sheet pentamethylbenzene from Sigma-Aldrich , accessed on March 26, 2017 ( PDF ).
  2. Julius v. Braun , Johannes Nelles: “Convenient synthesis of durol and pentamethylbenzene from crude xylene”, in: Reports of the German Chemical Society , 1934 , 67  (6), pp. 1094-1099; doi: 10.1002 / cber.19340670635 .

Web links