Rubidium dithionate

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Structural formula
2 Rubidium cation Structure of the dithionate anion
Crystal system

trigonal

Space group

P 321 (No. 150)Template: room group / 150

Lattice parameters

a = 1017 pm, c = 642 pm

General
Surname Rubidium dithionate
Molecular formula Rb 2 S 2 O 6
Brief description

colorless crystals

External identifiers / databases
CAS number 24079-72-9
Wikidata Q1500283
properties
Molar mass 331.06 g · mol -1
Physical state

firmly

density

2.89 g cm −3

safety instructions
GHS hazard labeling
no classification available
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Rubidium dithionate is the rubidium salt of the volatile dithionic acid .

Manufacturing

Rubidium dithionate can be made from rubidium carbonate and barium dithionate .

properties

Physical Properties

Rubidium dithionate crystallizes in the trigonal crystal system in the space group P 321 (space group no. 150) with the lattice parameters a = 1017 pm, c = 642 pm, and 3 formula units per unit cell . Template: room group / 150

Chemical properties

Like all dithionates, rubidium dithionate disproportionates into rubidium sulfate and sulfur dioxide when heated .

Rubidium difluorodithionate Rb 2 F 2 S 2 O 5 is formed with hydrofluoric acid and crystallizes out as a trihydrate.

Individual evidence

  1. ^ A b c Jean D'Ans, Ellen Lax: Pocket book for chemists and physicists. 3. Elements, inorganic compounds and materials, minerals, Volume 3. 4. Edition, Springer, 1997, ISBN 978-3-5406-0035-0 , p. 692 ( limited preview in Google book search).
  2. ↑ This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
  3. ^ R. Abegg, F. Auerbach: 'Handbuch der inorganic Chemie'. Verlag S. Hirzel, Vol. 2, 1908. P. 432. Full text
  4. ↑ RF Weinland, J. Alfa: "About fluorinated phosphates, sulfates, selenates, tellurates and dithionates" in Zeitschr. f. anorg. Chem. 1899 , 21 (1), p. 65 full text