Barium dithionate

Structural formula
General
Surname	Barium dithionate
Molecular formula	BaS 2 O 6
Brief description	colorless solid
External identifiers / databases
EC number	237-571-2
ECHA InfoCard	100.034.142
PubChem	21998054
Wikidata	Q4162425
properties
Molar mass	297.45 g mol −1
Physical state	firmly
density	4.54 g cm −3
solubility	easily soluble in water
safety instructions
GHS hazard labeling ; no classification available
GHS hazard labeling ; no classification available
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Barium dithionate is an inorganic chemical compound of barium from the group of dithionates .

Extraction and presentation

Barium dithionate can be obtained by reacting manganese dithionate solution with barium hydroxide .

{\ displaystyle \ mathrm {MnS_ {2} O_ {6} + Ba (OH) _ {2} \ longrightarrow BaS_ {2} O_ {6} + Mn (OH) _ {2}}}

properties

Barium dithionate, in the form of a dihydrate, is a colorless, air-stable solid that is easily soluble in water and insoluble in alcohol. When heated, the water of crystallization is released at 120 ° C, and from 140 ° C onwards there is a noticeable decomposition with evolution of sulfur dioxide and the formation of barium sulfate .

It has a monoclinic crystal structure with the space group C 2 / c (space group no. 15) . Template: room group / 15

Individual evidence

↑ ^a ^b ^c ^d ^e Georg Brauer (Ed.), With the collaboration of Marianne Baudler u. a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume I, Ferdinand Enke, Stuttgart 1975, ISBN 3-432-02328-6 , p. 396.
^ Dale L. Perry: Handbook of Inorganic Compounds, Second Edition . Taylor & Francis US, 2011, ISBN 1-4398-1462-7 , pp. 493 ( limited preview in Google Book search).
↑ This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
↑ JA Rausell-Colom, S. Garcia-Blanco: The crystal structure of barium dithionate dihydrate, BaSO.2HO. In: Acta Crystallographica. 21, 1966, pp. 672-675, doi : 10.1107 / S0365110X66003682 .

[brauer-1] Georg Brauer (Ed.), With the collaboration of Marianne Baudler u. a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume I, Ferdinand Enke, Stuttgart 1975, ISBN 3-432-02328-6 , p. 396.

[Dale_L._Perry-2] Dale L. Perry: Handbook of Inorganic Compounds, Second Edition . Taylor & Francis US, 2011, ISBN 1-4398-1462-7 , pp. 493 ( limited preview in Google Book search).

[NV-3] This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.

[DOI10.1107/S0365110X66003682-4] JA Rausell-Colom, S. Garcia-Blanco: The crystal structure of barium dithionate dihydrate, BaSO.2HO. In: Acta Crystallographica. 21, 1966, pp. 672-675, doi : 10.1107 / S0365110X66003682 .