Rubidium hydrogen sulfide

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Crystal structure
Crystal structure of rubidium hydrogen sulfide
__ Rb +      __ HS -
Crystal system

rhombohedral

Space group

R 3 m (No. 166)Template: room group / 166

Lattice parameters

a = 453.0 pm, β = 69.3 °

General
Surname Rubidium hydrogen sulfide
Ratio formula RbHS
Brief description

white, deliquescent needles

External identifiers / databases
CAS number 23317-41-1
Wikidata Q2171591
properties
Molar mass 118.54 g · mol -1
Physical state

firmly

safety instructions
GHS hazard labeling
no classification available
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Rubidium hydrogen sulfide is a rubidium salt of the hydrogen sulfide acid.

Manufacturing

Rubidium hydrogen sulfide can be obtained by introducing hydrogen sulfide into rubidium hydroxide solution.

properties

Physical Properties

Rubidium hydrogen sulfide crystallizes in the trigonal crystal system in the space group R 3 m (space group no. 166) with the lattice parameters a = 453.0 pm, β = 69.3 °, and 1 formula unit per unit cell . At 130 ° C there is a phase transition into a cubic crystal structure with the lattice parameter a = 692 pm, the space group Fm 3 m (No. 225) and 4 formula units per unit cell. Template: room group / 166Template: room group / 225

Chemical properties

Rubidium hydrogen sulfide reacts further with stoichiometric amounts of rubidium hydroxide to form rubidium sulfide .

Individual evidence

  1. ^ A b W. Blitz, E. Wilke-Dörfurt: "About sulfides of rubidium and cesium" in Zeitschr. f. anorg. Chem. 1906 . 48 , pp. 297-317. Full text
  2. ↑ This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
  3. ↑ a b R. Abegg, F. Auerbach: 'Handbuch der inorganic Chemie'. Verlag S. Hirzel, Vol. 2, 1908. P. 430. Full text
  4. ^ A b Jean D'Ans, Ellen Lax: Paperback for chemists and physicists. 3. Elements, inorganic compounds and materials, minerals, Volume 3. 4. Edition, Springer, 1997, ISBN 978-3-5406-0035-0 , pp. 692f. ( limited preview in Google Book search).