Titanium (II) bromide

Crystal structure
	__ Ti 2+ __ I -
General
Surname	Titanium (II) bromide
other names	Titanium dibromide
Ratio formula	TiBr 2
Brief description	black solid
External identifiers / databases
PubChem	123104
ChemSpider	109721
Wikidata	Q4096896
properties
Molar mass	207.68 g mol −1
Physical state	firmly
density	4.41 g cm −3
Melting point	500 ° C (decomposition)
solubility	Decomposes in water
safety instructions
GHS hazard labeling ; no classification available
GHS hazard labeling ; no classification available
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Titanium (II) bromide is an inorganic chemical compound of titanium from the group of bromides .

Extraction and presentation

Titanium (II) bromide can be produced by thermal decomposition of titanium (III) bromide

{\ displaystyle \ mathrm {2 \ TiBr_ {3} \ longrightarrow TiBr_ {2} + TiBr_ {4}}}

or obtained directly from the elements.

{\ displaystyle \ mathrm {Ti + Br_ {2} \ longrightarrow TiBr_ {2}}}

properties

Titanium (II) bromide is in the form of black crystals that catch fire in moist air and decompose in water to form the titanium (III) salt, forming hydrogen . It has a trigonal crystal structure of the cadmium (II) iodide type ( polytype 2H) with the space group P 3 m 1 (space group no.164 ) and the lattice parameters a = 362.9, c = 649.2 pm. Template: room group / 164

Individual evidence

↑ ^a ^b ^c ^d ^e ^f ^g Georg Brauer (Ed.), With the collaboration of Marianne Baudler u. a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume II, Ferdinand Enke, Stuttgart 1978, ISBN 3-432-87813-3 , p. 1336.
^ Jean D'Ans, Ellen Lax: Pocket book for chemists and physicists . Springer DE, 1997, ISBN 3-540-60035-3 , pp. 764 ( limited preview in Google Book search).
↑ This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
^ Paul Ehrlich, Walter Gutsche, Hans-Joachim Seifert: Representation and crystal structure of titanium dibromide. In: Journal of Inorganic and General Chemistry . 312, 1961, pp. 80-86, doi : 10.1002 / zaac.19613120112 .

[brauer-1] ↑ ^a ^b ^c ^d ^e ^f ^g Georg Brauer (Ed.), With the collaboration of Marianne Baudler u. a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume II, Ferdinand Enke, Stuttgart 1978, ISBN 3-432-87813-3 , p. 1336.

[Jean_D'Ans,_Ellen_Lax-2] Jean D'Ans, Ellen Lax: Pocket book for chemists and physicists . Springer DE, 1997, ISBN 3-540-60035-3 , pp. 764 ( limited preview in Google Book search).

[NV-3] This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.

[DOI10.1002/zaac.19613120112-4] Paul Ehrlich, Walter Gutsche, Hans-Joachim Seifert: Representation and crystal structure of titanium dibromide. In: Journal of Inorganic and General Chemistry . 312, 1961, pp. 80-86, doi : 10.1002 / zaac.19613120112 .