List of substances subject to authorization according to Annex XIV of the REACH regulation
The list of substances subject to authorization contains in Annex XIV of the REACH Regulation captured substances that allow the authorization requirement under stand.
As of February 27, 2020, the following 54 substances / groups of substances from the candidate list of the REACH regulation (SVHC list) have been included in Annex XIV. A further 48 substances are currently recommended for inclusion in Annex XIV.
| Entry no. | material | EC number | CAS number | property | Year of admission | Expiration date |
|---|---|---|---|---|---|---|
| 1 | 5- tert -Butyl-2,4,6-trinitro- m -xylene ( musk xylene) | 201-329-4 | 81-15-2 | vPvB | 2011 | 14 Aug 2014 |
| 2 | 4,4′-diaminodiphenylmethane (MDA) | 202-974-4 | 101-77-9 | Carcinogenic (Category 1B) | 2011 | 14 Aug 2014 |
| 3 |
Hexabromocyclododecane (HBCD) α-hexabromocyclododecane β-hexabromocyclododecane γ-hexabromocyclododecane |
221-695-9 247-148-4 |
3194-55-6 25637-99-4 134237-50-6 134237-51-7 134237-52-8 |
PBT | 2011 | Aug 21, 2015 |
| 4th | Bis (2-ethylhexyl) phthalate (DEHP) | 204-211-0 | 117-81-7 | Toxic for reproduction (Category 1B) | 2011 | Feb 21, 2015 |
| 5 | Benzyl butyl phthalate (BBP) | 201-622-7 | 85-68-7 | Toxic for reproduction (Category 1B) | 2011 | Feb 21, 2015 |
| 6th | Dibutyl phthalate (DBP) | 201-557-4 | 84-74-2 | Toxic for reproduction (Category 1B) | 2011 | Feb 21, 2015 |
| 7th | Diisobutyl phthalate (DIBP) | 201-553-2 | 84-69-5 | Toxic for reproduction (Category 1B) | 2012 | Feb 21, 2015 |
| 8th | Diarsenic trioxide | 215-481-4 | 1327-53-3 | Carcinogenic (Category 1A) | 2012 | May 21, 2015 |
| 9 | Diarsenic pentoxide | 215-116-9 | 1303-28-2 | Carcinogenic (Category 1A) | 2012 | May 21, 2015 |
| 10 | Lead chromate | 231-846-0 | 7758-97-6 | Carcinogenic (Category 1B) Toxic for reproduction (category 1A) |
2012 | May 21, 2015 |
| 11 |
Lead sulfochromate yellow (CI Pigment Yellow 34) |
215-693-7 | 1344-37-2 | Carcinogenic (Category 1B) Toxic for reproduction (category 1A) |
2012 | May 21, 2015 |
| 12 |
Lead chromate molybdate sulfate red (CI Pigment Red 104) |
235-759-9 | 12656-85-8 | Carcinogenic (Category 1B) Toxic for reproduction (category 1A) |
2012 | May 21, 2015 |
| 13 | Tris (2-chloroethyl) phosphate (TCEP) | 204-118-5 | 115-96-8 | Toxic for reproduction (Category 1B) | 2012 | Aug 21, 2015 |
| 14th | 2,4-dinitrotoluene (2,4-DNT) | 204-450-0 | 121-14-2 | Toxic for reproduction (Category 1B) | 2012 | Aug 21, 2015 |
| 15th | Trichlorethylene | 201-167-4 | 79-01-6 | Carcinogenic (Category 1B) | 2013 | Apr 21, 2016 |
| 16 | Chromium trioxide | 215-607-8 | 1333-82-0 | Carcinogenic (Category 1A) Mutagenic (Category 1B) |
2013 | 21 Sep 2017 |
| 17th |
Chromic acid Oligomers of chromic acid and dichromic acid , dichromic acid |
231-801-5 236-881-5 |
7738-94-5 13530-68-2 |
Carcinogenic (Category 1B) | 2013 | 21 Sep 2017 |
| 18th | Sodium dichromate | 234-190-3 | 7789-12-0 10588-01-9 |
Carcinogenic (Category 1B) Mutagenic (category 1B) |
2013 | 21 Sep 2017 |
| 19th | Potassium dichromate | 231-906-6 | 7778-50-9 | Carcinogenic (Category 1B) Mutagenic (category 1B) |
2013 | 21 Sep 2017 |
| 20th | Ammonium dichromate | 232-143-1 | 7789-09-5 | Carcinogenic (Category 1B) Mutagenic (category 1B) |
2013 | 21 Sep 2017 |
| 21st | Potassium chromate | 232-140-5 | 7789-00-6 | Carcinogenic (Category 1B) Mutagenic (category 1B) |
2013 | 21 Sep 2017 |
| 22nd | Sodium chromate | 231-889-5 | 7775-11-3 | Carcinogenic (Category 1B) Mutagenic (category 1B) |
2013 | 21 Sep 2017 |
| 23 | Formaldehyde, oligomeric reaction product with aniline |
500-036-1 | 25214-70-4 | Carcinogenic (Category 1B) | 2014 | 22 Aug 2017 |
| 24 | Arsenic acid | 231-901-9 | 7778-39-4 | Carcinogenic (Category 1A) | 2014 | 22 Aug 2017 |
| 25th | Bis (2-methoxyethyl) ether (diglyme) | 203-924-4 | 111-96-6 | Toxic for reproduction (Category 1B) | 2014 | 22 Aug 2017 |
| 26th | 1,2-dichloroethane | 203-458-1 | 107-06-2 | Carcinogenic (Category 1B) | 2014 | Nov 22, 2017 |
| 27 | 2,2'-dichloro-4,4'-methylenedianiline | 202-918-9 | 101-14-4 | Carcinogenic (Category 1B) | 2014 | Nov 22, 2017 |
| 28 | Dichromtris (chromate) | 246-356-2 | 24613-89-6 | Carcinogenic (Category 1B) | 2014 | Jan. 22, 2019 |
| 29 | Strontium chromate | 232-142-6 | 7789-06-2 | Carcinogenic (Category 1B) | 2014 | Jan. 22, 2019 |
| 30th |
Zinc potassium chromate Potassium hydroxyoctaoxo-dizincate dichromate |
234-329-8 | 11103-86-9 | Carcinogenic (Category 1A) | 2014 | Jan. 22, 2019 |
| 31 | Pentazine chromate octahydroxide | 256-418-0 | 49663-84-5 | Carcinogenic (Category 1A) | 2014 | Jan. 22, 2019 |
| 32 | 1-bromopropane ( n- propyl bromide) | 203-445-0 | 106-94-5 | Toxic for reproduction (Category 1B) | 2017 | 4th July 2020 |
| 33 | Diisopentyl phthalate | 210-088-4 | 605-50-5 | Toxic for reproduction (Category 1B) | 2017 | 4th July 2020 |
| 34 | 1,2- Benzene dicarboxylic acid, di-C 6–8 -branched alkyl esters, C 7 -rich (DIHP) | 276-158-1 | 71888-89-6 | Toxic for reproduction (Category 1B) | 2017 | 4th July 2020 |
| 35 | 1,2-benzene dicarboxylic acid, di-C 7-11 -branched and linear alkyl esters (DHNUP) | 271-084-6 | 68515-42-4 | Toxic for reproduction (Category 1B) | 2017 | 4th July 2020 |
| 36 | 1,2-benzenedicarboxylic acid, dipentyl ester, branched and linear | 284-032-2 | 84777-06-0 | Toxic for reproduction (Category 1B) | 2017 | 4th July 2020 |
| 37 | Bis (2-methoxyethyl) phthalate | 204-212-6 | 117-82-8 | Toxic for reproduction (Category 1B) | 2017 | 4th July 2020 |
| 38 | Dipentyl phthalate | 205-017-9 | 131-18-0 | Toxic for reproduction (Category 1B) | 2017 | 4th July 2020 |
| 39 | n -pentyl isopentyl phthalate | - | 776297-69-9 | Toxic for reproduction (Category 1B) | 2017 | 4th July 2020 |
| 40 | Anthracene oil | 292-602-7 | 90640-80-5 | Carcinogenic (Category 1B) PBT vPvB |
2017 | 4th Oct 2020 |
| 41 | Bad luck, coal tar, high temperature | 266-028-2 | 65996-93-2 | Carcinogenic (Category 1B) PBT vPvB |
2017 | 4th Oct 2020 |
| 42 | 4- (1,1,3,3-tetramethylbutyl) phenol , ethoxylated | - | - | Endocrine disrupting effects on the environment (Article 57 (f)) |
2017 | Jan. 4, 2021 |
| 43 | 4-nonylphenol, branched and linear, ethoxylated | - | - | Endocrine disrupting effects on the environment (Article 57 (f)) |
2017 | Jan. 4, 2021 |
| 44 | 1,2-Benzene dicarboxylic acid, dihexyl ester, branched and linear | 271-093-5 | 68515-50-4 | Toxic for reproduction (Category 1B) | 2020 | Feb. 27, 2023 |
| 45 | Dihexyl phthalate | 201-559-5 | 84-75-3 | Toxic for reproduction (Category 1B) | 2020 | Feb. 27, 2023 |
| 46 | 1,2-benzene dicarboxylic acid, di-C 6-10 alkyl ester; 1,2-benzene dicarboxylic acid, mixed decyl, hexyl and octyl diesters with ≥ 0.3% dihexyl phthalate | 271-094-0 272-013-1 |
68515-51-5 68648-93-1 |
Toxic for reproduction (Category 1B) | 2020 | Feb. 27, 2023 |
| 47 | Trixylyl phosphate | 246-677-8 | 25155-23-1 | Toxic for reproduction (Category 1B) | 2020 | May 27, 2023 |
| 48 | Sodium perborate ; Perboric acid, sodium salt | 239-172-9 234-390-0 |
- | Toxic for reproduction (Category 1B) | 2020 | May 27, 2023 |
| 49 | Sodium peroxometaborate | 231-556-4 | 7632-04-4 | Toxic for reproduction (Category 1B) | 2020 | May 27, 2023 |
| 50 | 5- sec -Butyl-2- (2,4-dimethylcyclohex-3-en-1-yl) -5-methyl-1,3-dioxane [1], 5- sec -butyl-2- (4,6- dimethylcyclohex-3-en-1-yl) -5-methyl-1,3-dioxane [2] [covers every single stereoisomer of [1] and [2] or every combination thereof] | - | - | vPvB | 2020 | 27 Aug 2023 |
| 51 | 2- (2 H -benzotriazol-2-yl) -4,6-di- tert -pentylphenol (UV-328) | 247-384-8 | 25973-55-1 | PBT vPvB |
2020 | Nov 27, 2023 |
| 52 | 2,4-Di- tert -butyl-6- (5-chlorobenzotriazol-2-yl) phenol (UV-327) | 223-383-8 | 3864-99-1 | vPvB | 2020 | Nov 27, 2023 |
| 53 | 2- (2 H -Benzotriazol-2-yl) -4- ( tert -butyl) -6- ( sec -butyl) phenol (UV-350) | 253-037-1 | 36437-37-3 | vPvB | 2020 | Nov 27, 2023 |
| 54 | 2-Benzotriazol-2-yl-4,6-di- tert -butylphenol (UV-320) | 223-346-6 | 3846-71-7 | PBT vPvB |
2020 | Nov 27, 2023 |
- ↑ Time from which the placing on the market and use of the substance without authorization is prohibited.
Switzerland
In Switzerland, the entries from the EU register of substances subject to authorization - after additional clarifications by authorities and industry - are included in Annex 1.17 of the Chemical Risk Reduction Ordinance (ORRChem).
Web links
- ECHA - PREPARATION OF DRAFT ANNEX XIV ENTRIES FOR SUBSTANCES RECOMMENDED TO BE INCLUDED IN ANNEX XIV
- ECHA approval. In: echa.europa.eu.
- ECHA recommendation for inclusion in the list of substances subject to authorization. In: echa.europa.eu.
- ECHA - Annex XIV of the REACH regulation - List of substances subject to authorization
Individual evidence
- ↑ ECHA: Annex XIV of the REACH regulation - List of substances subject to authorization , accessed on February 12, 2020.
- ↑ REACH-CLP-Biocide Helpdesk: Annex XIV of the REACH regulation , accessed on January 7, 2019.
- ↑ Previous recommendations - ECHA. In: echa.europa.eu. July 10, 2019, accessed March 7, 2020 .
- ↑ a b c d e f Regulation (EU) No. 143/2011
- ↑ a b c d e f g h Regulation (EU) No. 125/2012
- ↑ a b c d e f g h Regulation (EU) No. 348/2013
- ↑ a b c d e f g h i Regulation (EU) No. 895/2014
- ↑ a b c d e f g h i j k l Regulation (EU) 2017/999
- ↑ a b c d e f g h i j k Regulation (EU) 2020/171
- ↑ Registration office for chemicals: List of substances of very high concern (SVHC). Retrieved April 3, 2020 .