Xenon trifluoridohexafluoroantimonate (V)

Structural formula
	No drawing available
General
Surname	Xenon trifluoridohexafluoroantimonate (V)
Molecular formula	XeF 3 [SbF 6 ]
Brief description	yellow-greenish crystals
External identifiers / databases
Wikidata	Q25404204
properties
Molar mass	424.04 g mol −1
Physical state	firmly
density	3.92 g · cm -3
Melting point	110 ° C
safety instructions
GHS hazard labeling ; no classification available
GHS hazard labeling ; no classification available
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Xenon trifluoridohexafluoroantimonate (V) , XeF ₃ [SbF ₆ ] is a chemical compound between the xenon trifluoride ion XeF ₃⁺ and the hexafluoroantimonic acid H [SbF ₆ ].

Extraction and presentation

The compound can be obtained by dissolving xenon tetrafluoride XeF ₄ and antimony pentafluoride SbF ₅ in hydrofluoric acid HF. The ratio of the solution is 3.4: 1.

properties

Xenon trifluoridohexafluoroantimonate is a solid consisting of yellow-greenish crystals. Its density is 3.92 g · cm ⁻³ . The crystal structure of the compound is monoclinic .

literature

RJ Gillepsie, B. Landa, GJ Schrobilgen: Raman spectral studies of .alpha.- and .beta.-trifluoroxenone hexafluoroantimonates, trifluoroxenone (1+) undecafluorodiantimonate (1-), trifluoroxenone (1+), hexafluoroarsenate (1-), trifluoroarsenate (1-), 1+) hexafluoroantimonate (1-) and undecafluorodiantimonate (1-), and fluorodioxoxenon (1+) undecafluorodiantimonate (1-) . In: Inorganic Chemistry . June 1976, p. 1256 , doi : 10.1021 / ic50160a003 .
RJ Gillepsie, GJ Schrobilgen: Trifluoroxenon (1+), trifluorooxoxenon (1 + 0), and fluorodioxoxenon (1+) cations. Preparation and characterization by fluorine-19 nuclear magnetic resonance spectroscopy . In: Inorganic Chemistry . October 1974, p. 2370 , doi : 10.1021 / ic50140a015 .
DE McKee, CJ Adams, Neil Bartlett: Preparation and Raman spectra of the salts [XeF3 +] [SbF6-], [XeF3 +] [Sb2F11-], [XeOF3 +] [SbF6-] and [XeOF3 +] [Sb2F11-] . In: Inorganic Chemistry . August 1973, p. 1722 , doi : 10.1021 / ic50126a003 .

Individual evidence

↑ ^a ^b ^c David R. Lide: CRC Handbook of Chemistry and Physics: A Ready-reference Book of Chemical and Physical Data . CRC Press, 1995, ISBN 0-8493-0595-0 , pp. 4-94 .
↑ This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
↑ ^a ^b P. Boldrini, RJ Gillepsie, PR Ireland, GJ Schrobilgen: Crystal structure of trifluoroxenon (1+) hexafluoroantimonate (1-) . In: Inorganic Chemistry . July 1974, p. 1690 , doi : 10.1021 / ic50137a030 .

[BUCH1-1] David R. Lide: CRC Handbook of Chemistry and Physics: A Ready-reference Book of Chemical and Physical Data . CRC Press, 1995, ISBN 0-8493-0595-0 , pp. 4-94 .

[NV-2] This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.

[BUCH2-3] P. Boldrini, RJ Gillepsie, PR Ireland, GJ Schrobilgen: Crystal structure of trifluoroxenon (1+) hexafluoroantimonate (1-) . In: Inorganic Chemistry . July 1974, p. 1690 , doi : 10.1021 / ic50137a030 .