Gallocyanin

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Structural formula
Structural formula of gallocyanin
General
Surname Gallocyanin
other names

7-dimethylamino-4-hydroxy-3-oxo-phenoxazine-1-carboxylic acid

Molecular formula C 15 H 13 ClN 2 O 5
Brief description

black solid

External identifiers / databases
CAS number 1562-85-2
EC number 216-345-7
ECHA InfoCard 100.014.860
PubChem 73801
ChemSpider 21429647
Wikidata Q19597271
properties
Molar mass 336.73 g mol −1
Physical state

firmly

solubility

sparingly soluble in hot water, ethanol and glacial acetic acid

safety instructions
GHS labeling of hazardous substances
07 - Warning

Caution

H and P phrases H: 302
P: no P-phrases
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Gallocyanin is a chemical compound from the group of phenoxazine dyes .

Extraction and presentation

Gallocyanin can be obtained by reacting nitrosodimethylaniline with gallic acid .

properties

Gallocyanin is a black solid that is sparingly soluble in hot water. Alkalis easily dissolve it with reddish-purple color.

use

Gallocyanin is used for calico printing and wool dyeing. With alum it forms a chelate complex , which in gallocyanin-alum stain for nucleic acids is used. This was introduced in 1921 by Ernst Siegfried Becher .

Individual evidence

  1. a b c d e data sheet Gallocyanin, Dye content 90% from Sigma-Aldrich , accessed on October 14, 2018 ( PDF ).
  2. ^ A b Rudolf Nietzki: Chemistry of organic dyes . BoD - Books on Demand, 2017, p. 223 ( limited preview in Google Book search).
  3. a b Georg Lunge, Ernst Berl: Chemical-technical investigation methods . tape 3 . Springer-Verlag, 2013, ISBN 978-3-662-38269-1 , pp. 1071 ( limited preview in Google Book search).
  4. S. Becher: Investigations on real staining of cell nuclei with artificial stain dyes and the theory of the histological staining process with dissolved lacquers. Borntraeger brothers, Berlin 1921.
  5. Hans Lyon: Theory and Strategy in Histochemistry - A Guide to the Selection and Understanding of Techniques . Springer Science & Business Media, 2012, ISBN 978-3-642-73742-8 , pp. 117 ( limited preview in Google Book search).
  6. L. Heilmeyer: Blood and Blood Diseases . Part 1: General Hematology and Physiopathology of the Erythrocytic System . Springer-Verlag, 2013, ISBN 978-3-642-95036-0 , pp. 141 ( limited preview in Google Book search).