Laccainic acids

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The laccainic acids are anthraquinone derivatives and the coloring components of the red dye Lac Dye , which is obtained from the lacquer scale insects . The mixture of laccainic acids AE is also known as CI Natural Red 25 (natural red 25).

Chemical structures

The laccainic acids are a group of five anthraquinone dyes that are contained in the insect dye Lac Dye. In addition to the main component laccainic acid A , these include laccainic acids B – E:

Laccainic acids
Surname Laccainic Acid A. Laccainic acid B Laccainic acid C Laccainic acid D Laccainic acid E.
Structural formula Laccaic Acid A.svg Laccaic Acid B.svg Laccaic Acid C.svg Laccaic Acid D.svg Laccaic Acid E.svg
Molecular formula C 26 H 19 NO 12 C 24 H 16 O 12 C 25 H 17 NO 13 C 16 H 10 O 7 C 24 H 17 NO 11
Molar mass 537.44 g mol −1 496.38 g mol −1 539.41 g mol −1 314.25 g mol −1 495.40 g mol −1
CAS number 15979-35-8 17249-00-2 23241-56-7 18499-84-8 14597-16-1
60687-93-6 (mixture of laccainic acid A – E)
Wikidata Q27162387 Q27162389 Q27162390 Q27162392 -
Q60982962 (mixture of laccainic acid A – E)

Occurrence and use

Paint scale insects

Like carminic acid or kermess acid, laccainic acids are insect pigments obtained from scale insects. They are the colored components of Lac Dye.

Individual evidence

  1. ^ Lac Dye. materialarchiv.ch, accessed on December 10, 2018 .
  2. Entry on laccainic acid. In: Römpp Online . Georg Thieme Verlag, accessed on March 5, 2019.
  3. Mark C. Whiting: The dyes in early oriental carpets . In: Society of German Chemists (ed.): Chemistry in our time . 15th year, no. 6 . Verlag Chemie GmbH, Weinheim 1981, p. 179-189 .
  4. Perey Brigl: The chemical research into natural dyes . Springer Fachmedien, Wiesbaden 1921, ISBN 978-3-663-03907-5 , p. 43 ff . ( limited preview in Google Book search). doi : 10.1007 / 978-3-663-05096-4