Lithium hexafluoroantimonate (V)

Crystal structure
	__ Li + __ Sb 5+ __ F -
Crystal system	rhombohedral
Space group	R 3 (No. 148)
Lattice parameters	a = 5.43 Å, α = 56 ° 58 ', Z = 1
Coordination numbers	[6] Sb, [6] Li
General
Surname	Lithium hexafluoroantimonate (V)
Ratio formula	Li [SbF 6 ]
Brief description	white powder
External identifiers / databases
EC number	670-363-3
ECHA InfoCard	100.196.093
PubChem	16700586
Wikidata	Q61941693
properties
Molar mass	242.68 g mol −1
Physical state	firmly
density	3.2-3.5 g · cm −3
Melting point	decomposes
solubility	soluble in water
safety instructions
H and P phrases	H: 302-332-411
	P: 261-264-273-301 + 330 + 331-304 + 340-312-391-501
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Lithiumhexafluoroantimonat , Li [SbF ₆ ], the lithium - salt of hexafluoroantimonic H [SbF ₆ ].

use

The salt is used as a photoinitiator for the production of polymers .

properties

Lithium hexafluoroantimonate is a white powder with a density between 3.2 g · cm ⁻³ and 3.5 g · cm ⁻³ . It is soluble in water.

The compound crystallizes in the rhombohedral space group R 3 (space group no. 148) with the lattice constants a = 5.43 Å, α = 56 ° 58 ', Z = 1. The structure corresponds to a rhombohedral distorted NaSbF ₆ type. Template: room group / 148

safety instructions

The compound is toxic if swallowed or inhaled .

Combustion products of the compound are hydrogen fluoride , lithium oxide and antimony oxides .

literature

NJ Dudney (Ed.): Battery / Energy Technology (General) - 215th ECS Meeting . Issue 25. The Electrochemical Society, 2009. ISBN 1566777674 . Pp. 15-22

Individual evidence

↑ ^a ^b ^c data sheet Lithium Hexafluoroantimonate from AmericanElements, accessed March 2, 2019.
↑ ^a ^b ^c ^d ^e ^f ^g data sheet Lithium hexafluoroantimonate from AlfaAesar, accessed on March 2, 2019 ( PDF )(JavaScript required) .
^ John H. Burns: The Crystal Structure of Lithium Fluoroantimonate (V) . In: Acta Crystallographica . tape 15 , 1962, pp. 1098-1101 , doi : 10.1107 / S0365110X62002935 .

[AMERICANELEMENTS-1] ta sheet Lithium Hexafluoroantimonate from AmericanElements, accessed March 2, 2019.

[ALFA-2] ↑ ^a ^b ^c ^d ^e ^f ^g data sheet Lithium hexafluoroantimonate from AlfaAesar, accessed on March 2, 2019 ( PDF )(JavaScript required) .

[3] John H. Burns: The Crystal Structure of Lithium Fluoroantimonate (V) . In: Acta Crystallographica . tape 15 , 1962, pp. 1098-1101 , doi : 10.1107 / S0365110X62002935 .