Lithium hexafluoroarsenate (V)

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Structural formula
Lithium ion Structure of the hexafluoroarsenate ion
General
Surname Lithium hexafluoroarsenate (V)
Molecular formula Li [AsF 6 ]
Brief description

White dust

External identifiers / databases
CAS number 29935-35-1
EC number 249-963-0
ECHA InfoCard 100.045.406
PubChem 9837036
ChemSpider 8012757
Wikidata Q3732745
properties
Molar mass 195.85 g mol −1
Physical state

firmly

solubility

Insoluble in water

safety instructions
GHS labeling of hazardous substances
06 - Toxic or very toxic 09 - Dangerous for the environment

danger

H and P phrases H: 301 + 331-410
P: 261-273-301 + 310-311-501
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Lithium hexafluoroarsenate (V) , Li [AsF 6 ] is a salt of lithium from the group of hexafluoroarsenates .

use

Lithium hexafluoroarsenate (V) is a potential electrolyte material for batteries.

properties

In methyl acetate, the salt has a conductivity that remains between −20 ° C and 50 ° C.

safety instructions

The compound is toxic if ingested or inhaled .

Strong oxidizing agents and reducing agents as well as strong acids and bases cause violent reactions with lithium hexafluoroarsenate (V). The decomposition produces hydrogen fluoride , arsenic oxides and lithium oxide .

literature

  • Donald L. Wise: Electrical and Optical Polymer Systems: Fundamentals: Methods, and Applications Plastics Engineering . CRC Press, 1998, ISBN 1-4822-6988-0 , pp. 802-805 .

Individual evidence

  1. a b c d e data sheet Lithium hexafluoroarsenate (V) from Sigma-Aldrich , accessed on March 17, 2019 ( PDF ).
  2. a b c data sheet Lithium hexafluoroarsenate (V) from AlfaAesar, accessed on March 17, 2019 ( PDF )(JavaScript required) .
  3. Elena Yu, Tyunina, Marina D. Chekunova: Electrochemical properties of lithium hexafluoroarsenate in methyl acetate at various temperatures . In: Journal of Molecular Liquids . November 2013, p. 332–336 , doi : 10.1016 / j.molliq.2013.08.019 .