Manganese (III) fluoride

Crystal structure
	__ Mn 3+ __ F -
General
Surname	Manganese (III) fluoride
other names	Manganese trifluoride
Ratio formula	MnF 3
Brief description	ruby red solid
External identifiers / databases
EC number	232-006-6
ECHA InfoCard	100.029.096
PubChem	82213
Wikidata	Q419682
properties
Molar mass	111.93 g mol −1
Physical state	firmly
density	3.54 g cm −3 (25)
Melting point	600 ° C (decomposition)
solubility	Hydrolysis in water
safety instructions
H and P phrases	H: 272-301-312-315-319-332-335
	P: 220-261-280-301 + 310-305 + 351 + 338
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Manganese (III) fluoride is a chemical compound of manganese from the group of fluorides .

Extraction and presentation

Manganese (III) fluoride can be obtained by reacting manganese (II) iodide or manganese (II) fluoride with fluorine .

{\ displaystyle \ mathrm {2 \ MnI_ {2} +13 \ F_ {2} \ longrightarrow 2 \ MnF_ {3} +4 \ IF_ {5}}}

It can be produced by fluorinating manganese.

{\ displaystyle \ mathrm {2 \ Mn + 3 \ F_ {2} \ longrightarrow 2 \ MnF_ {3}}}

properties

Manganese (III) fluoride is a ruby red salt that is hydrolyzed by water. It is thermally resistant up to 600 ° C. It has a monoclinic pseudorhombohedral crystal structure with the space group C 2 / c (space group no. 15) , which is made up of elongated MnF ₆ octahedra. The lattice parameters are a = 8.904 ± 0.003 Å ; b = 5.037 ± 0.002 Å; c = 13.448 ± 0.005 Å; β = 92.74 ± 0.04 °. Template: room group / 15

use

Manganese (III) fluoride is used as a fluorinating agent.

Individual evidence

↑ ^a ^b ^c ^d ^e data sheet Manganese (III) fluoride, 99.9% trace metals basis from Sigma-Aldrich , accessed on July 10, 2012 ( PDF ).
↑ ^a ^b ^c ^d Georg Brauer (Ed.), With the collaboration of Marianne Baudler a . a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume I, Ferdinand Enke, Stuttgart 1975, ISBN 3-432-02328-6 , p. 268.
↑ webelements: WebElements Periodic Table of the Elements | Manganese | chemical reaction data
↑ Erwin Riedel, Christoph Janiak: Inorganic Chemistry . Walter de Gruyter, 2011, ISBN 3-11-022566-2 , p. 831 ( limited preview in Google Book search).
^ MA Hepworth, KH Jack, RS Nyholm: Interatomic Bonding in Manganese Trifluoride. In: Nature. 179, 1957, pp. 211-212, doi : 10.1038 / 179211b0 .
^ MA Hepworth, KH Jack: The crystal structure of manganese trifluoride, MnF3 In: Acta Crystallographica. 10, 1957, pp. 345-351, doi : 10.1107 / S0365110X57001024 .
↑ Investigation of Manganese Trifluoride - Thermal Decomposition by Knudsen Cell Mass Spectrometry (PDF; 6 kB)

[Sigma-1] ↑ ^a ^b ^c ^d ^e data sheet Manganese (III) fluoride, 99.9% trace metals basis from Sigma-Aldrich , accessed on July 10, 2012 ( PDF ).

[brauer-2] Georg Brauer (Ed.), With the collaboration of Marianne Baudler a . a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume I, Ferdinand Enke, Stuttgart 1975, ISBN 3-432-02328-6 , p. 268.

[webelements-3] webelements: WebElements Periodic Table of the Elements | Manganese | chemical reaction data

[Erwin_Riedel,_Christoph_Janiak-4] Erwin Riedel, Christoph Janiak: Inorganic Chemistry . Walter de Gruyter, 2011, ISBN 3-11-022566-2 , p. 831 ( limited preview in Google Book search).

[DOI10.1038/179211b0-5] MA Hepworth, KH Jack, RS Nyholm: Interatomic Bonding in Manganese Trifluoride. In: Nature. 179, 1957, pp. 211-212, doi : 10.1038 / 179211b0 .

[DOI10.1107/S0365110X57001024-6] MA Hepworth, KH Jack: The crystal structure of manganese trifluoride, MnF3 In: Acta Crystallographica. 10, 1957, pp. 345-351, doi : 10.1107 / S0365110X57001024 .

[7] Investigation of Manganese Trifluoride - Thermal Decomposition by Knudsen Cell Mass Spectrometry (PDF; 6 kB)