Sodium tantalate

Crystal structure
	No drawing available
General
Surname	Sodium tantalate
other names	Sodium tantalum oxide; Sodium metatantalate;
Ratio formula	NaTaO 3
Brief description	white solid
External identifiers / databases
ECHA InfoCard	100,031,623
PubChem	166006
Wikidata	Q63341315
properties
Molar mass	251.94 g mol −1
Physical state	firmly
density	7 g cm −3
safety instructions
GHS hazard labeling ; no classification available
GHS hazard labeling ; no classification available
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Sodium tantalate is an inorganic chemical compound of sodium from the group of tantalates .

Extraction and presentation

Sodium tantalate can be obtained by reacting sodium hydroxide or sodium carbonate with tantalum (V) oxide at 1200 ° C.

properties

Sodium tantalate is a white solid. It has a perovskite crystal structure with the space group P 2 / m (space group no. 10) or space group Pcmn (space group no. 62, position 4) . Further crystal structures occur at higher temperatures. Template: room group / 10 Template: room group / 62.4

use

Sodium tantalate can be used as a photocatalyst . By reacting with lead (II) chloride , lead (II) tantalate can be obtained.

Individual evidence

^ ^A ^b Dale L. Perry: Handbook of Inorganic Compounds . CRC Press, 2016, ISBN 978-1-4398-1462-8 , pp. 385 ( limited preview in Google Book Search).
↑ R. Blachnik: Pocket book for chemists and physicists Volume 3: Elements, inorganic compounds and materials, minerals . Springer-Verlag, 2013, ISBN 978-3-642-58842-6 , pp. 628 ( limited preview in Google Book search).
↑ This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
↑ Toshiyuki Yokoi, Junya Sakuma et al. a .: Preparation of a colloidal array of NaTaO3 nanoparticles via a confined space synthesis route and its photocatalytic application. In: Physical Chemistry Chemical Physics. 13, 2011, p. 2563, doi : 10.1039 / C0CP02141E .
↑ ^a ^b Wan-Hsien Lin, Ching Cheng u. a .: NaTaO3 photocatalysts of different crystalline structures for water splitting into H2 and O2. In: Applied Physics Letters. 89, 2006, p. 211904, doi : 10.1063 / 1.2396930 .
↑ M. Ahtee, L. Unonius: The structure of NaTaO3 by X-ray powder diffraction. In: Acta Crystallographica Section A. 33, 1977, p. 150, doi : 10.1107 / S056773947700031x .
↑ HF Kay, JL Miles: The structure of cadmium titanate and sodium tantalate. In: Acta Crystallographica. 10, p. 213, doi : 10.1107 / S0365110X57000663 .
↑ Brendan J Kennedy, AK Prodjosantoso, Christopher J Howard: Powder neutron diffraction study of the high temperature phase transitions in NaTaO3. In: Journal of Physics: Condensed Matter. 11, 1999, p. 6319, doi : 10.1088 / 0953-8984 / 11/33/302 .
↑ Tobias Grewe, Harun Tüysüz: Amorphous and Crystalline Sodium Tantalate Composites for Photocatalytic Water Splitting. In: ACS Applied Materials & Interfaces. 7, 2015, p. 23153, doi : 10.1021 / acsami.5b06965 .
↑ Likun Pan, Guang Zhu: Perovskite Materials Synthesis, Characterization, Properties, and Applications . BoD - Books on Demand, 2016, ISBN 978-953-512-245-6 , pp. 495 ( limited preview in Google Book search).
↑ Jonathan Boltersdorf, Tricia Wong, Paul A. Maggard: Synthesis and Optical Properties of Ag (I), Pb (II), and Bi (III) Tantalate-Based Photocatalysts. In: ACS Catalysis. 3, 2013, p. 2943, doi : 10.1021 / cs400707x .

[Dale_L._Perry-1] A ^b Dale L. Perry: Handbook of Inorganic Compounds . CRC Press, 2016, ISBN 978-1-4398-1462-8 , pp. 385 ( limited preview in Google Book Search).

[R._Blachnik-2] R. Blachnik: Pocket book for chemists and physicists Volume 3: Elements, inorganic compounds and materials, minerals . Springer-Verlag, 2013, ISBN 978-3-642-58842-6 , pp. 628 ( limited preview in Google Book search).

[NV-3] This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.

[DOI10.1039/C0CP02141E-4] Toshiyuki Yokoi, Junya Sakuma et al. a .: Preparation of a colloidal array of NaTaO3 nanoparticles via a confined space synthesis route and its photocatalytic application. In: Physical Chemistry Chemical Physics. 13, 2011, p. 2563, doi : 10.1039 / C0CP02141E .

[DOI10.1063/1.2396930-5] Wan-Hsien Lin, Ching Cheng u. a .: NaTaO3 photocatalysts of different crystalline structures for water splitting into H2 and O2. In: Applied Physics Letters. 89, 2006, p. 211904, doi : 10.1063 / 1.2396930 .

[DOI10.1107/S056773947700031x-6] M. Ahtee, L. Unonius: The structure of NaTaO3 by X-ray powder diffraction. In: Acta Crystallographica Section A. 33, 1977, p. 150, doi : 10.1107 / S056773947700031x .

[DOI10.1107/S0365110X57000663-7] HF Kay, JL Miles: The structure of cadmium titanate and sodium tantalate. In: Acta Crystallographica. 10, p. 213, doi : 10.1107 / S0365110X57000663 .

[DOI10.1088/0953-8984/11/33/302-8] Brendan J Kennedy, AK Prodjosantoso, Christopher J Howard: Powder neutron diffraction study of the high temperature phase transitions in NaTaO3. In: Journal of Physics: Condensed Matter. 11, 1999, p. 6319, doi : 10.1088 / 0953-8984 / 11/33/302 .

[DOI10.1021/acsami.5b06965-9] Tobias Grewe, Harun Tüysüz: Amorphous and Crystalline Sodium Tantalate Composites for Photocatalytic Water Splitting. In: ACS Applied Materials & Interfaces. 7, 2015, p. 23153, doi : 10.1021 / acsami.5b06965 .

[Likun_Pan,_Guang_Zhu-10] Likun Pan, Guang Zhu: Perovskite Materials Synthesis, Characterization, Properties, and Applications . BoD - Books on Demand, 2016, ISBN 978-953-512-245-6 , pp. 495 ( limited preview in Google Book search).

[DOI10.1021/cs400707x-11] Jonathan Boltersdorf, Tricia Wong, Paul A. Maggard: Synthesis and Optical Properties of Ag (I), Pb (II), and Bi (III) Tantalate-Based Photocatalysts. In: ACS Catalysis. 3, 2013, p. 2943, doi : 10.1021 / cs400707x .