Osmium pentacarbonyl
| Structural formula | |||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
|
|
|||||||||||||
| General | |||||||||||||
| Surname | Osmium pentacarbonyl | ||||||||||||
| other names |
Osmium (V) carbonyl |
||||||||||||
| Molecular formula | Os (CO) 5 | ||||||||||||
| Brief description |
yellow liquid |
||||||||||||
| External identifiers / databases | |||||||||||||
|
|||||||||||||
| properties | |||||||||||||
| Molar mass | 330.28 g mol −1 | ||||||||||||
| Physical state |
liquid |
||||||||||||
| Melting point |
2-2.5 ° C |
||||||||||||
| safety instructions | |||||||||||||
|
|||||||||||||
| As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . | |||||||||||||
Osmium pentacarbonyl , Os (CO) 5 is a metal complex consisting of the pentavalent osmium and the carbonyl complex .
Extraction
Similar to ruthenium pentacarbonyl , osmium pentacarbonyl is also produced by triosmium dodecacarbonyl and carbon monoxide at 200 times atmospheric pressure and 280 ° C.
properties
As a solid, osmium (V) carbonyl is present as white-yellow crystals. The complex is also more robust than ruthenium pentacarbonyl and decomposes only starting from 80 ° C to tetraoxide .
Individual evidence
- ^ A b c d Paul Rushman, Gilbert N. Van Buuren, Mahmoud Shiralian, Roland K. Pomeroy: Properties of the pentacarbonyls of ruthenium and osmium . Organometallics, May 1983, pp. 693 , doi : 10.1021 / om00077a026 .
- ↑ This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.