Osmium pentacarbonyl

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Structural formula
Structural formula of osmium pentacarbonyl
General
Surname Osmium pentacarbonyl
other names

Osmium (V) carbonyl

Molecular formula Os (CO) 5
Brief description

yellow liquid

External identifiers / databases
CAS number 16406-49-8
PubChem 10892861
ChemSpider 9068124
Wikidata Q4348643
properties
Molar mass 330.28 g mol −1
Physical state

liquid

Melting point

2-2.5 ° C

safety instructions
GHS hazard labeling
no classification available
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Osmium pentacarbonyl , Os (CO) 5 is a metal complex consisting of the pentavalent osmium and the carbonyl complex .

Extraction

Similar to ruthenium pentacarbonyl , osmium pentacarbonyl is also produced by triosmium dodecacarbonyl and carbon monoxide at 200 times atmospheric pressure and 280 ° C.

properties

As a solid, osmium (V) carbonyl is present as white-yellow crystals. The complex is also more robust than ruthenium pentacarbonyl and decomposes only starting from 80 ° C to tetraoxide .

Individual evidence

  1. ^ A b c d Paul Rushman, Gilbert N. Van Buuren, Mahmoud Shiralian, Roland K. Pomeroy: Properties of the pentacarbonyls of ruthenium and osmium . Organometallics, May 1983, pp. 693 , doi : 10.1021 / om00077a026 .
  2. This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.