Piperettine
Structural formula | ||||||||||
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General | ||||||||||
Surname | Piperettine | |||||||||
other names |
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Molecular formula | C 19 H 21 NO 3 | |||||||||
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properties | ||||||||||
Molar mass | 315.41 g mol −1 | |||||||||
Physical state |
firmly |
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Melting point |
146 ° C |
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solubility |
almost insoluble in acids |
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safety instructions | ||||||||||
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As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . |
Piperettine is a chemical compound from the group of alkaloids and piperine derivatives .
Occurrence
Piperettine occurs naturally to 0.4-0.8% in pepper and contributes to the sharp taste. It was isolated from black pepper by Spring and Stark in 1850.
Extraction and presentation
Piperettine can be obtained from piperonal by a Ramberg-Bäcklund reaction .
Web links
- A Critical Study of two Procedures for the Determination of Piperine in Black and White Pepper (PDF; 572 kB) CHRISTIANE GENEST, D. MORISON SMITH, and DG CHAPMAN;
Individual evidence
- ^ A b c Quality Assurance In Spices And Spice Products . Allied, 1999, ISBN 978-81-7023-896-6 , pp. 116 ( limited preview in Google Book search).
- ↑ This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
- ↑ Gerald Rimbach, Jennifer Möhring, Helmut F. Erbersdobler: Food and goods knowledge for beginners . Springer, 2010, ISBN 978-3-642-04485-4 , pp. 274 ( limited preview in Google Book search).
- ↑ Yang LI, Yu ZHANG, Xiao Long WANG, Zhi HUANG, Xiao Ping CAO, Chinese Chemical Letters Vol. 15, no. 6, pp. 631–634, 2004, Stereoselective Synthesis of Piperamide Alkaloids by Modified Ramberg-Bäcklund Reaction ( page no longer available , search in web archives ) Info: The link was automatically marked as defective. Please check the link according to the instructions and then remove this notice. (PDF; 100 kB).
- ↑ Synthesis of Piperine Analogues ( Memento of October 21, 2012 in the Internet Archive ) (PDF; 232 kB).