Ruthenium (III) fluoride

Crystal structure
	No drawing available
General
Surname	Ruthenium (III) fluoride
other names	Ruthenium trifluoride
Ratio formula	RuF 3
Brief description	dark brown solid
External identifiers / databases
PubChem	12011490
Wikidata	Q24629073
properties
Molar mass	158.0 g mol −1
Physical state	firmly
density	5.36 g cm −3
Melting point	600 ° C (decomposition)
solubility	practically soluble in water
safety instructions
GHS hazard labeling ; no classification available
GHS hazard labeling ; no classification available
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Ruthenium (III) fluoride is a chemical compound of ruthenium from the group of fluorides .

Extraction and presentation

Ruthenium (III) fluoride can be obtained by reacting ruthenium (V) fluoride with iodine at 250 ° C or with sulfur at> 200 ° C.

{\ displaystyle {\ ce {5 RuF5 + I2 -> 5 RuF3 + 2 IF5}}}

properties

Ruthenium (III) fluoride is a dark brown solid that is practically insoluble in water. It has a crystal structure with the space group R 3 c (space group no. 167) . It forms octahedral fluorocomplexes. Template: room group / 167

Individual evidence

↑ ^a ^b ^c R. Blachnik: Pocket book for chemists and physicists Volume 3: Elements, inorganic compounds and materials, minerals . Springer-Verlag, 2013, ISBN 978-3-642-58842-6 , pp. 700 ( limited preview in Google Book Search).
^ ^A ^b William M. Haynes: CRC Handbook of Chemistry and Physics . CRC Press, 2014, ISBN 978-1-4822-0868-9 , pp. 86 ( limited preview in Google Book search).
↑ This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
↑ ^a ^b A. F. Holleman: Textbook of inorganic chemistry . Walter de Gruyter GmbH & Co KG, 2019, ISBN 978-3-11-083817-6 , pp. 1418 ( limited preview in Google Book search).
^ EA Seddon, KR Seddon: The Chemistry of Ruthenium . Elsevier, 2013, ISBN 978-1-4832-8990-8 , pp. 155 ( limited preview in Google Book search).
↑ MA Hepworth, KH Jack u. a .: The crystal structures of the trifluorides of iron, cobalt, ruthenium, rhodium, palladium and iridium. In: Acta Crystallographica. 10, 1957, p. 63, doi : 10.1107 / S0365110X57000158 .

[R._Blachnik-1] R. Blachnik: Pocket book for chemists and physicists Volume 3: Elements, inorganic compounds and materials, minerals . Springer-Verlag, 2013, ISBN 978-3-642-58842-6 , pp. 700 ( limited preview in Google Book Search).

[William_M._Haynes-2] A ^b William M. Haynes: CRC Handbook of Chemistry and Physics . CRC Press, 2014, ISBN 978-1-4822-0868-9 , pp. 86 ( limited preview in Google Book search).

[NV-3] This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.

[A._F._Holleman-4] A. F. Holleman: Textbook of inorganic chemistry . Walter de Gruyter GmbH & Co KG, 2019, ISBN 978-3-11-083817-6 , pp. 1418 ( limited preview in Google Book search).

[E.A._Seddon,_K.R._Seddon-5] EA Seddon, KR Seddon: The Chemistry of Ruthenium . Elsevier, 2013, ISBN 978-1-4832-8990-8 , pp. 155 ( limited preview in Google Book search).

[DOI10.1107/S0365110X57000158-6] MA Hepworth, KH Jack u. a .: The crystal structures of the trifluorides of iron, cobalt, ruthenium, rhodium, palladium and iridium. In: Acta Crystallographica. 10, 1957, p. 63, doi : 10.1107 / S0365110X57000158 .