Silver bromate

Structural formula
General
Surname	Silver bromate
other names	Silver (I) bromate
Molecular formula	AgBrO 3
Brief description	white solid
External identifiers / databases
CAS number 7783-89-3 EC number 232-032-8 ECHA InfoCard 100.029.120 PubChem 9878022 Wikidata Q2658632
properties
Molar mass	235.77 g mol −1
Physical state	firmly
density	5.206 g cm −3  (25 ° C)
solubility	poorly soluble in water (0.196 g / 100 ml at 25 ° C) soluble in ammonium hydroxide easily soluble in ammonia
safety instructions
GHS labeling of hazardous substances danger H and P phrases H: 272-315-319-335 P: 220-261-305 + 351 + 338
Thermodynamic properties
ΔH f 0	−10.5 kJ / mol
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Silver bromate is an inorganic chemical compound of silver from the group of bromates .

Extraction and presentation

Silver bromate can be obtained by reacting silver nitrate with a bromate solution (e.g. from potassium bromate ).

${\displaystyle \mathrm {AgNO_{3}+KBrO_{3}\longrightarrow AgBrO_{3}\downarrow +KNO_{3}} }$

properties

Silver bromate is a white, light-sensitive solid that is poorly soluble in water. It decomposes when heated. It has a tetragonal crystal structure with the space group I 4 / m (space group no. 87) and the lattice parameters a = 860 pm and c = 809 pm as well as eight formula units per unit cell .

use

Silver bromate is used as an oxidizing agent to convert tetrahydropyranyl ethers into carbonyl compounds.

Individual evidence

1. ↑ ^{a b c d e f} data sheet Silver bromate, 97% from Sigma-Aldrich , accessed on July 25, 2013 ( PDF ).
2. ↑ Peter. Ruoff, Margit. Varga, Endre. Koros (1987) Silver bromate precipitation in bromate oscillators treated with excess silver ion. A comment. J. Phys. Chem., 91 (16), 4431-4432. doi : 10.1021 / j100300a047
3. ↑ Michelle Davidson: Inorganic Chemistry . Lotus Press, 2006, ISBN 81-89093-39-8 , pp. 170 ( limited preview in Google Book search).
4. ^ ^{A b} G. Charlot, RG Murray: Qualitative Inorganic Analysis . CUP Archives, 1954, p. 87 ( limited preview in Google Book search).
5. ↑ David R. Lide (Ed.): CRC Handbook of Chemistry and Physics . 90th edition. (Internet version: 2010), CRC Press / Taylor and Francis, Boca Raton, FL, Standard Thermodynamic Properties of Chemical Substances, pp. 5-4.
6. ^ Dale L. Perry: Handbook of Inorganic Compounds, Second Edition . Taylor & Francis, 2011, ISBN 1-4398-1462-7 , pp. 365 ( limited preview in Google Book Search).
7. ↑ Roger Blachnik (Ed.): Paperback for chemists and physicists . Volume III: Elements, Inorganic Compounds and Materials, Minerals . founded by Jean d'Ans, Ellen Lax. 4th, revised and revised edition. Springer, Berlin 1998, ISBN 3-540-60035-3 , pp. 282 ( limited preview in Google Book search).